Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Details of Molecule thiocyanate (in MeCN)

For reactivities of structurally related compounds go to: Nucleophiles » N-Nucleophiles » Other N-centered nucleophiles
Structure image of molecule
Molecule class Nucleophiles » N-Nucleophiles » Other N-centered nucleophiles
Quality *
Parameters N  Parameter: 12.13
sN Parameter: 0.60
Comment

Ambident nucleophile, S reactivity: N = 17.94, sN = 0.60. N was determined with reference electrophiles, however sN was estimated to be identical as for the S-attack.

Sum formula CNS
Solvent MeCN
Reference J. Am. Chem. Soc. 2003, 125, 14126-14132
DOI: 10.1021/ja037317u