Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Details of Molecule (4-MeO)-tritylium ion

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles » Carbocations » Triarylcarbenium Ions
Structure image of molecule
Molecule class Electrophiles » C-Electrophiles » Carbocations » Triarylcarbenium Ions
Quality -
Parameters E Parameter: -1.59
Comment E was determined from and for reactions with n-nucleophiles (not reference nucleophiles). E must not be used for predicting reactivitites toward pi-nucleophiles. The previously reported value of E = –1.87 (JACS 2003, 125, 286.) was based on only two reactions and should be revised.
Reference Eur. J. Org. Chem. 2011, , 6470-6475
DOI: 10.1002/ejoc.201100910