Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Enol Ethers

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles
Found 46 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
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(3,3,4,4,5,5,6,6,7,7,7-undecafluoro)-2-(trimethylsiloxy)hept-1-ene
dichloromethaneN  Parameter: -3.52
sN Parameter: 1.17
***Org. Lett. 2012, 14, 3990-3993
DOI: 10.1021/ol301766w
image of molecule

(triisopropylsiloxy)ethene
dichloromethaneN  Parameter: 3.44
sN Parameter: 0.94
**J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(tris(trimethylsilyl)siloxy)ethene
dichloromethaneN  Parameter: 4.01
sN Parameter: 0.83
***Org. Lett. 2010, 12, 5206-5209
DOI: 10.1021/ol102220e
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(Z)-1-(triisopropylsiloxy)propen
dichloromethaneN  Parameter: 3.87
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1,1-bis(trimethylsiloxy)propene
dichloromethaneN  Parameter: 10.38
sN Parameter: 0.87
****Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
image of molecule

1,1-diethoxyethene
dichloromethaneN  Parameter: 9.81
sN Parameter: 0.81
***Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
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1,2-bis(trimethylsiloxy)cyclohexene
dichloromethaneN  Parameter: 4.46
sN Parameter: 1.15
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1-(perfluorophenyl)-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 1.47
sN Parameter: 0.89
***Org. Lett. 2012, 14, 3990-3993
DOI: 10.1021/ol301766w
image of molecule

1-(trimethylsiloxy)buta-1,3-diene
dichloromethaneN  Parameter: 4.60
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1-(trimethylsiloxy)cycloheptene
dichloromethaneN  Parameter: 6.62
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-(trimethylsiloxy)cyclohexene
dichloromethaneN  Parameter: 5.21
sN Parameter: 1.00
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

1-(trimethylsiloxy)cyclooctene
dichloromethaneN  Parameter: 6.77
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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1-(trimethylsiloxy)cyclopentene
dichloromethaneN  Parameter: 6.57
sN Parameter: 0.93
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
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1-(triphenylsiloxy)cyclopentene
dichloromethaneN  Parameter: 5.76
sN Parameter: 1.02
****Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
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1-(tris(pentafluorophenyl)siloxy)-cyclopentene
dichloromethaneN  Parameter: 1.38
sN Parameter: 0.93
*Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
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1-(tris(trimethylsilyl)siloxy)cyclohexene
dichloromethaneN  Parameter: 5.07
sN Parameter: 0.91
***Org. Lett. 2010, 12, 5206-5209
DOI: 10.1021/ol102220e
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1-butoxy-1-(t-butyl-dimethylsiloxy)ethene
dichloromethaneN  Parameter: 10.32
sN Parameter: 0.79
****Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
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1-butoxy-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 10.21
sN Parameter: 0.82
****Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
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1-methoxy-2-methyl-1-(trimethylsiloxy)propene
dichloromethaneN  Parameter: 9.00
sN Parameter: 0.98
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
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1-methoxy-2-methyl-1-(trimethylsiloxy)propene (in MeCN)
MeCNN  Parameter: 9.11
sN Parameter: 0.88
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

1-phenoxy-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 8.23
sN Parameter: 0.81
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

1-phenyl-1-(trimethylsiloxy)ethene
dichloromethaneN  Parameter: 6.22
sN Parameter: 0.96
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
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2,3-dihydrofuran
dichloromethaneN  Parameter: 4.37
sN Parameter: 0.90
****Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
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2-(tert.butyldimethylsiloxy)propene
dichloromethaneN  Parameter: 5.58
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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2-(triisopropylsiloxy)propene
dichloromethaneN  Parameter: 5.38
sN Parameter: 0.85
**J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2-(trimethylsiloxy)-5,6-dihydro-4H-pyran
dichloromethaneN  Parameter: 10.61
sN Parameter: 0.86
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
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2-(trimethylsiloxy)-5,6-dihydro-4H-pyran (in MeCN)
MeCNN  Parameter: 10.52
sN Parameter: 0.78
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

2-(trimethylsiloxy)buta-1,3-diene
dichloromethaneN  Parameter: 4.83
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-(trimethylsiloxy)furan
dichloromethaneN  Parameter: 7.22
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-(trimethylsiloxy)propene
dichloromethaneN  Parameter: 5.41
sN Parameter: 0.91
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2-(triphenylsiloxy)propene
dichloromethaneN  Parameter: 4.46
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-(tris(pentafluorophenyl)siloxy)-propene
dichloromethaneN  Parameter: 0.58
sN Parameter: 0.91
*Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
image of molecule

2-(tris(trimethylsilyl)siloxy)propene
dichloromethaneN  Parameter: 6.04
sN Parameter: 0.82
***Org. Lett. 2010, 12, 5206-5209
DOI: 10.1021/ol102220e
image of molecule

2-methyl-1-(trimethylsiloxy)propen
dichloromethaneN  Parameter: 3.94
sN Parameter: 1.00
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

3,3,3-trifluoro-2-(trimethylsiloxy)propene
dichloromethaneN  Parameter: -2.94
sN Parameter: 1.11
***Org. Lett. 2012, 14, 3990-3993
DOI: 10.1021/ol301766w
image of molecule

3,3-dimethyl-2-(trimethylsiloxy)buten
dichloromethaneN  Parameter: 3.78
sN Parameter: 0.79
**J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

3-methyl-2-(trimethylsiloxy)but-1-ene
dichloromethaneN  Parameter: 5.41
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

4-methyl-5-(trimethylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 11.50
sN Parameter: 0.91
***Eur. J. Org. Chem. 2004, , 2791-2796
DOI: 10.1002/ejoc.200400134
image of molecule

5-(trimethylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 12.56
sN Parameter: 0.70
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

5-(trimethylsiloxy)-2,3-dihydrofuran (in MeCN)
MeCNN  Parameter: 12.34
sN Parameter: 0.72
***J. Am. Chem. Soc. 2013, 135, 6579-6587
DOI: 10.1021/ja401106x
image of molecule

5-(triphenylsiloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 11.28
sN Parameter: 0.91
***Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
image of molecule

5-(tris(pentafluorophenyl)siloxy)-2,3-dihydrofuran
dichloromethaneN  Parameter: 8.16
sN Parameter: 0.67
***Eur. J. Org. Chem. 2005, , 1760-1764
DOI: 10.1002/ejoc.200400706
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ethyl-vinylether
dichloromethaneN  Parameter: 3.92
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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isobutylenyl-ethylether
dichloromethaneN  Parameter: 4.23
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
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n-butyl vinyl ether
dichloromethaneN  Parameter: 3.76
sN Parameter: 0.91
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
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Z-3-(trimethylsiloxy)pent-2-ene
dichloromethaneN  Parameter: 5.58
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c