Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Carbanions in other solvents

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions
Found 15 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
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anion of (3-nitrophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.75
sN Parameter: 0.71
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of (4-cyanophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.92
sN Parameter: 0.74
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of (4-nitrophenyl)nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.05
sN Parameter: 0.72
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of 2-nitropropane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 12.20
sN Parameter: 0.71
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 20.72
sN Parameter: 0.58
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
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anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 19.49
sN Parameter: 0.63
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
image of molecule

anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.24
sN Parameter: 0.66
***J. Am. Chem. Soc. 2007, 129, 9753-9761
DOI: 10.1021/ja072135b
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anion of dimethyl malonate (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.24
sN Parameter: 0.64
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
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anion of ethyl cyanoacetate (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.59
sN Parameter: 0.65
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of malononitrile (in 91M9AN)
MeOH-MeCN mixN  Parameter: 18.21
sN Parameter: 0.69
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
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anion of nitroethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.41
sN Parameter: 0.67
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
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anion of nitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 14.02
sN Parameter: 0.61
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of p-tolylnitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 13.58
sN Parameter: 0.64
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
image of molecule

anion of phenylnitromethane (in 91M9AN)
MeOH-MeCN mixN  Parameter: 12.51
sN Parameter: 0.67
***Eur. J. Org. Chem. 2006, , 2530-2537
DOI: 10.1002/ejoc.200500769
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cyanide (in MeCN)
MeCNN  Parameter: 16.27
sN Parameter: 0.70
***Angew. Chem. Int. Ed. 2005, 44, 142-145
DOI: 10.1002/anie.200461640