Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

S-Ylides

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Ylides
Found 10 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

Me2S(O)=CH2 (in DMSO)
DMSON  Parameter: 21.29
sN Parameter: 0.47
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

Me2S=CH(4-CN-C6H4) (in DMSO)
DMSON  Parameter: 21.07
sN Parameter: 0.68
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

Me2S=CH(p-NO2-C6H4) (in DMSO)
DMSON  Parameter: 18.42
sN Parameter: 0.65
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

Me2S=CH-CN (in DMSO)
DMSON  Parameter: 16.23
sN Parameter: 0.60
***Chem. Eur. J. 2010, 16, 8610-8614
DOI: 10.1002/chem.201001455
image of molecule

Me2S=CH-CO2Et (in DMSO)
DMSON  Parameter: 15.85
sN Parameter: 0.61
***Chem. Eur. J. 2010, 16, 8610-8614
DOI: 10.1002/chem.201001455
image of molecule

(4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO)
DMSON  Parameter: 15.68
sN Parameter: 0.65
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

(4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO)
DMSON  Parameter: 14.48
sN Parameter: 0.71
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

(C6H5)-(CO)-CH=SMe2 (in DMSO)
DMSON  Parameter: 13.95
sN Parameter: 0.69
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

(4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO)
DMSON  Parameter: 13.78
sN Parameter: 0.72
***J. Am. Chem. Soc. 2010, 132, 17894-17900
DOI: 10.1021/ja1084749
image of molecule

(4-Br-C6H4)-(CO)-CH=SMe2
dichloromethaneN  Parameter: 11.95
sN Parameter: 0.76
***Angew. Chem. Int. Ed. 2009, 48, 5034-5037
DOI: 10.1002/anie.200900933