Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

H-B hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles
Found 23 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

borane-2,6-lutidine-complex
dichloromethaneN  Parameter: 10.33
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-4-methoxypyridine-complex
dichloromethaneN  Parameter: 11.01
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-4-tBu-pyridine-complex
dichloromethaneN  Parameter: 10.46
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-DMAP-complex
dichloromethaneN  Parameter: 12.44
sN Parameter: 0.76
***Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-N,N-diethylaniline-complex
dichloromethaneN  Parameter: 8.53
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-N,N-diisopropylaniline-complex
dichloromethaneN  Parameter: 8.84
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-N-ethyl-N-isopropylaniline-complex
dichloromethaneN  Parameter: 9.12
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-pyridine-complex
dichloromethaneN  Parameter: 10.01
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

borane-triethylamine-complex
dichloromethaneN  Parameter: 8.90
sN Parameter: 0.75
***J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

borane-trimethylamine-complex
dichloromethaneN  Parameter: 7.97
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

bromoborane-triethylamine-complex
dichloromethaneN  Parameter: 7.49
sN Parameter: 0.75
*Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

Bu4NBH4 (in DMSO)
DMSON  Parameter: 14.94
sN Parameter: 0.79
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
DOI: 10.1002/anie.200804263
image of molecule

cyanoborate ion (in water)
waterN  Parameter: 12.10
sN Parameter: 0.79
-Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

dipp Imd boronate
dichloromethaneN  Parameter: 9.55
sN Parameter: 0.81
***Org. Lett. 2012, 14, 82-85
DOI: 10.1021/ol202836p
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KBH4 (in DMSO)
DMSON  Parameter: 15.14
sN Parameter: 0.77
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
DOI: 10.1002/anie.200804263
image of molecule

Me2 Imd boronate
dichloromethaneN  Parameter: 11.88
sN Parameter: 0.71
***Org. Lett. 2012, 14, 82-85
DOI: 10.1021/ol202836p
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NaB(OAc)3H (in DMSO)
DMSON  Parameter: 14.45
sN Parameter: 0.76
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
DOI: 10.1002/anie.200804263
image of molecule

NaBH3(CN) (in DMSO)
DMSON  Parameter: 11.52
sN Parameter: 0.67
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
DOI: 10.1002/anie.200804263
image of molecule

NaBH4 (in DMSO)
DMSON  Parameter: 14.74
sN Parameter: 0.81
***Angew. Chem. Int. Ed. 2009, 48, 1958-1961
DOI: 10.1002/anie.200804263
image of molecule

tetrahydroborate ion (in water)
waterN  Parameter: 10.80
sN Parameter: 0.60
-Chem. Eur. J. 2013, 19, 249-263
DOI: 10.1002/chem.201202839
image of molecule

[H-B(2,4,6-F3C6H2)3]- [NEt4]+
MeCNN  Parameter: 14.13
sN Parameter: 0.61
***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
DOI: 10.1002/anie.201507298
image of molecule

[H-B(2,6-F2C6H3)3]- [NEt4]+
MeCNN  Parameter: 13.97
sN Parameter: 0.66
***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
DOI: 10.1002/anie.201507298
image of molecule

[H-B(C6F5)3]- [NEt4]+
MeCNN  Parameter: 10.04
sN Parameter: 0.73
***Angew. Chem. Int. Ed. 2015, 54, 14508-14512
DOI: 10.1002/anie.201507298