Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Mono-enes

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Alkenes
Found 44 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

6-(julolidin-9-yl)fulvene
MeCNN  Parameter: 7.79
sN Parameter: 1.06
***Eur. J. Org. Chem. 2009, , 1202-1206
DOI: 10.1002/ejoc.200801099
image of molecule

6-(4-dimethylamino-phenyl)fulvene
MeCNN  Parameter: 6.72
sN Parameter: 0.87
***Eur. J. Org. Chem. 2009, , 1202-1206
DOI: 10.1002/ejoc.200801099
image of molecule

6,6-dimethylfulvene
MeCNN  Parameter: 3.93
sN Parameter: 0.88
***Eur. J. Org. Chem. 2009, , 1202-1206
DOI: 10.1002/ejoc.200801099
image of molecule

methylenecyclooctane
dichloromethaneN  Parameter: 3.16
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecyclopentane
dichloromethaneN  Parameter: 2.82
sN Parameter: 0.90
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

methylenecyclodecane
dichloromethaneN  Parameter: 2.82
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-cyclopropylpropene
dichloromethaneN  Parameter: 2.60
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecyclononane
dichloromethaneN  Parameter: 2.57
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

alpha-methylstyrene
dichloromethaneN  Parameter: 2.35
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecycloundecane
dichloromethaneN  Parameter: 2.33
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecycloheptane
dichloromethaneN  Parameter: 2.24
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-methyl-4-vinyl-benzene
dichloromethaneN  Parameter: 1.70
sN Parameter: 1.06
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

methylenecyclopentadecane
dichloromethaneN  Parameter: 1.69
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2,6-dimethyl-hepta-1,6-diene
dichloromethaneN  Parameter: 1.69
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecyclobutane
dichloromethaneN  Parameter: 1.65
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2,7-dimethylocta-1,7-diene
dichloromethaneN  Parameter: 1.58
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

methylenecyclododecane
dichloromethaneN  Parameter: 1.52
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-methylcyclopentene
dichloromethaneN  Parameter: 1.18
sN Parameter: 1.17
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

methylenecyclohexane
dichloromethaneN  Parameter: 1.16
sN Parameter: 1.04
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

2,5-dimethyl-hexa-1,5-diene
dichloromethaneN  Parameter: 1.14
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-methylpropene (isobutylene)
dichloromethaneN  Parameter: 1.11
sN Parameter: 0.98
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2-methyl-but-1-ene
dichloromethaneN  Parameter: 1.00
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2-methyl-pent-1-ene
dichloromethaneN  Parameter: 0.84
sN Parameter: 1.06
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

2,4,4-trimethyl-pent-1-ene
dichloromethaneN  Parameter: 0.79
sN Parameter: 1.07
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

styrene
dichloromethaneN  Parameter: 0.78
sN Parameter: 0.95
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(1S)-(-)-alpha-pinene
dichloromethaneN  Parameter: 0.68
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

2,4,6-trimethylstyrene
dichloromethaneN  Parameter: 0.68
sN Parameter: 1.09
***Macromolecules 2005, 38, 33-40
DOI: 10.1021/ma048389o
image of molecule

2-methyl-but-2-ene
dichloromethaneN  Parameter: 0.65
sN Parameter: 1.17
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2,3-dimethyl-but-1-ene
dichloromethaneN  Parameter: 0.65
sN Parameter: 1.00
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

2,4-dimethyl-penta-1,4-diene
dichloromethaneN  Parameter: 0.54
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

(2-methylallyl)benzene
dichloromethaneN  Parameter: 0.25
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-methylcyclohexene
dichloromethaneN  Parameter: 0.08
sN Parameter: 1.15
*****J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

2,3,3-trimethyl-but-1-ene
dichloromethaneN  Parameter: 0.06
sN Parameter: 1.07
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

norbornene
dichloromethaneN  Parameter: -0.25
sN Parameter: 1.09
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

methylenecyclopropane
dichloromethaneN  Parameter: -0.47
sN Parameter: 0.90
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

(E)-propenylbenzene
dichloromethaneN  Parameter: -0.49
sN Parameter: 1.18
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

tetramethylethylene
dichloromethaneN  Parameter: -1.00
sN Parameter: 1.40
***Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

(Z)-phenylpropene
dichloromethaneN  Parameter: -1.07
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

cyclopentene
dichloromethaneN  Parameter: -1.55
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

propene
dichloromethaneN  Parameter: -2.41
sN Parameter: 1.00
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

(Z)-but-2-ene
dichloromethaneN  Parameter: -2.44
sN Parameter: 1.09
**J. Am. Chem. Soc. 2001, 123, 9500-9512
DOI: 10.1021/ja010890y
image of molecule

(E)-but-2-ene
dichloromethaneN  Parameter: -2.45
sN Parameter: 1.10
*Acc. Chem. Res. 2003, 36, 66-77
DOI: 10.1021/ar020094c
image of molecule

1-hexene
dichloromethaneN  Parameter: -2.77
sN Parameter: 1.41
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

2-chloropropene
dichloromethaneN  Parameter: -3.65
sN Parameter: 1.97
*****J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b