Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Other solvents (pure or mixtures)

For reactivities of structurally related compounds go to: Nucleophiles » O-Nucleophiles » Alcohols and aqueous solvents
Found 11 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

H2O (in water)
waterN  Parameter: 5.20
sN Parameter: 0.89
***J. Am. Chem. Soc. 2004, 126, 5174-5181
DOI: 10.1021/ja031828z
image of molecule

10% water/90% acetone (v/v)
water-acetone mixN  Parameter: 5.70
sN Parameter: 0.85
***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
DOI: 10.1002/anie.200353468
image of molecule

20% water/80% acetone (v/v)
water-acetone mixN  Parameter: 5.77
sN Parameter: 0.87
***Angew. Chem. Int. Ed. 2004, 43, 2302-2305
DOI: 10.1002/anie.200353468
image of molecule

trifluoroethanol
TFEN  Parameter: 1.11
sN Parameter: 0.96
***J. Am. Chem. Soc. 2012, 134, 13902-13911
DOI: 10.1021/ja306522b
image of molecule

methanol
MeOHN  Parameter: 7.54
sN Parameter: 0.92
***J. Am. Chem. Soc. 2004, 126, 5174-5181
DOI: 10.1021/ja031828z
image of molecule

ethanol
EtOHN  Parameter: 7.44
sN Parameter: 0.90
***J. Am. Chem. Soc. 2004, 126, 5174-5181
DOI: 10.1021/ja031828z
image of molecule

91% n-propanol/9% MeCN (v/v)
nPrOH-MeCN mixN  Parameter: 7.05
sN Parameter: 0.80
***Can. J. Chem. 2005, 83, 1554-1560
DOI: 10.1139%2Fv05-170
image of molecule

91% propan-2-ol/9% MeCN (v/v)
iPrOH-MeCN mixN  Parameter: 6.49
sN Parameter: 0.96
***Can. J. Chem. 2005, 83, 1554-1560
DOI: 10.1139%2Fv05-170
image of molecule

DMSO (O attack)
DMSON  Parameter: 11.30
sN Parameter: 0.74
***J. Am. Chem. Soc. 2009, 131, 11392-11401
DOI: 10.1021/ja903207b
image of molecule

isopropanol (in MeCN)
MeCNN  Parameter: 6.82
sN Parameter: 0.70
***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
DOI: 10.1246/bcsj.20170360
image of molecule

tert-butanol (in MeCN)
MeCNN  Parameter: 5.35
sN Parameter: 0.72
***Bull. Chem. Soc. Jpn. 2018, 91, 523-530
DOI: 10.1246/bcsj.20170360