Mayr's Database Of Reactivity Parameters
AK Prof. Mayr

Acceptor-Substituted Ethylenes

For reactivities of structurally related compounds go to: Electrophiles » C-Electrophiles
Found 93 Molecules.
Molecule Solvent Reactivity Parameters Classification Reference (sort by title or year)
image of molecule

(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -13.88
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

(2-phenylethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -12.93
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

(E)-1,3-diphenylprop-2-en-1-one (in DMSO)
DMSOE Parameter: -19.39
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

(E)-1-methyl-4-(styrylsulfonyl)benzene (in DMSO)
DMSOE Parameter: -24.69
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
DMSOE Parameter: -17.64
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)
DMSOE Parameter: -17.33
***J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one
DMSOE Parameter: -19.15
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO)
DMSOE Parameter: -19.36
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO)
DMSOE Parameter: -19.17
*J. Am. Chem. Soc. 2011, 133, 8240-8251
DOI: 10.1021/ja200820m
image of molecule

(E)-4-phenylbut-3-en-2-one (in DMSO)
DMSOE Parameter: -23.01
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

(ethene-1,1-diyldisulfonyl)dibenzene
DMSOE Parameter: -7.50
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

1,2-diaza-1,3-diene 1a
DMSOE Parameter: -13.28
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1b
DMSOE Parameter: -13.90
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1c
DMSOE Parameter: -14.91
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1d
DMSOE Parameter: -15.38
***Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1e
MeOHE Parameter: -14.90
*Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1,2-diaza-1,3-diene 1f
MeOHE Parameter: -15.30
*Chem. Eur. J. 2010, 16, 12008-12016
DOI: 10.1002/chem.201000828
image of molecule

1-phenylprop-2-en-1-one (in DMSO)
DMSOE Parameter: -15.25
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -14.50
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -15.03
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone
0E Parameter: -14.36
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone
0E Parameter: -17.18
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone
0E Parameter: -16.38
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone
0E Parameter: -16.36
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone
0E Parameter: -11.87
***Eur. J. Org. Chem. 2009, , 3203-3211
DOI: 10.1002/ejoc.200900299
image of molecule

2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide
DMSOE Parameter: -14.55
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide
DMSOE Parameter: -13.02
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-(p-(dimethylamino)benzylidene)-indan-1,3-dione
0E Parameter: -13.56
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2-(p-methoxybenzylidene)-indan-1,3-dione
0E Parameter: -11.32
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2-benzylidene-indan-1,3-dione
0E Parameter: -10.11
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide
DMSOE Parameter: -11.78
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

2-phenylethene-1-sulfonyl fluoride
DMSOE Parameter: -16.63
***Angew. Chem. Int. Ed. 2016, 55, 12644-12667
DOI: 10.1002/anie.201601875
image of molecule

4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline
DMSOE Parameter: -16.53
***Chem. Asian J. 2012, 7, 1401-1407
DOI: 10.1002/asia.201101046
image of molecule

4-bromo-<i>trans-beta</i>-nitrostyrene
E Parameter: -13.37
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-cyano-<i>trans-beta</i>-nitrostyrene
E Parameter: -12.61
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-methoxy-<i>trans-beta</i>-nitrostyrene
E Parameter: -14.70
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-methyl-<i>trans-beta</i>-nitrostyrene
E Parameter: -14.23
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
image of molecule

4-nitro-<i>trans-beta</i>-nitrostyrene
E Parameter: -12.37
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
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<i>trans-beta</i>-nitrostyrene
E Parameter: -13.85
***J. Org. Chem. 2011, 76, 9370-9378
DOI: 10.1021/jo201678u
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acrylonitrile (in DMSO)
DMSOE Parameter: -19.05
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

acylazolium ion
E Parameter: -11.52
***Angew. Chem. Int. Ed. 2012, 51, 5234-5238
DOI: 10.1002/anie.201109042
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ani(Br)2QM
0E Parameter: -8.63
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

ani(Ph)2QM
0E Parameter: -12.18
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

ani(t-Bu)2QM
E Parameter: -16.11
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
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aniBBS
0E Parameter: -10.37
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
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benzylidene-Meldrum's acid
0E Parameter: -9.15
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

benzylidenemalononitril
0E Parameter: -9.42
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

bh 6f
E Parameter: -18.90
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh 6i
E Parameter: -19.10
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh 6k
E Parameter: -18.20
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh 6l
E Parameter: -18.90
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh 6m
E Parameter: -17.30
*Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh6a
E Parameter: -18.60
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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bh6j
E Parameter: -17.90
**Chem. Eur. J. 2010, 16, 1365-1371
DOI: 10.1002/chem.200902487
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but-3-en-2-one (in DMSO)
DMSOE Parameter: -16.76
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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cinnamonitrile (in DMSO)
DMSOE Parameter: -24.60
*J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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diethyl 2-((1-methyl-1,2,3,4-tetrahydroquinolin-6-yl)methylene)malonate
0E Parameter: -23.40
*Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl 2-((julolidine-9-yl)methylene)malonate
0E Parameter: -23.80
*Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl 3-chloro-benzylidene malonate
0E Parameter: -18.98
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl 4-(dimethylamino)benzylidene malonate
0E Parameter: -23.10
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-cyano-benzylidene malonate
0E Parameter: -18.06
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl 4-methoxy-benzylidene malonate
0E Parameter: -21.47
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl 4-methyl-benzylidene malonate
0E Parameter: -21.11
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl 4-nitrobenzylidene malonate
0E Parameter: -17.67
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
image of molecule

diethyl benzylidene malonate
0E Parameter: -20.55
***Chem. Eur. J. 2008, 14, 9675-9682
DOI: 10.1002/chem.200801277
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diethyl fumarate
DMSOE Parameter: -17.79
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
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diethyl maleate
DMSOE Parameter: -19.49
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
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dma(Ph)2QM
0E Parameter: -13.39
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

dma(S)BBS
0E Parameter: -10.73
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

dma(t-Bu)2QM
E Parameter: -17.29
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

dmaBBS
0E Parameter: -12.76
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

ethenesulfonyl fluoride (ESF)
DMSOE Parameter: -12.09
***Angew. Chem. Int. Ed. 2016, 55, 12644-12667
DOI: 10.1002/anie.201601875
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ethenylsulfonylbenzene (in DMSO)
DMSOE Parameter: -18.36
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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ethyl (E)-but-2-enoate (in DMSO)
DMSOE Parameter: -23.59
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

ethyl 2-methylprop-2-enoate (in DMSO)
DMSOE Parameter: -22.77
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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ethyl cinnamate (in DMSO)
DMSOE Parameter: -24.52
**J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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ethyl prop-2-enoate (in DMSO)
DMSOE Parameter: -19.07
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
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fumaronitrile
DMSOE Parameter: -15.71
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
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jul Meldrum's acid
0E Parameter: -13.97
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

jul(S)BBS
0E Parameter: -11.89
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
image of molecule

jul(t-Bu)2QM
0E Parameter: -17.90
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P
image of molecule

jul-indan-1,3-dione
0E Parameter: -14.68
***Org. Biomol. Chem. 2007, 5, 3020-3026
DOI: 10.1039/b708025e
image of molecule

julBBS
0E Parameter: -13.84
***J. Org. Chem. 2007, 72, 9170-9180
DOI: 10.1021/jo071273g
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maleic anhydride
DMSOE Parameter: -11.31
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
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methyl prop-2-enoate (in DMSO)
DMSOE Parameter: -18.84
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

N,N-dimethylprop-2-enamide (in DMSO)
DMSOE Parameter: -23.54
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

N-methyl maleimide
DMSOE Parameter: -14.07
***Eur. J. Org. Chem. 2014, , 2956-2963
DOI: 10.1002/ejoc.201301779
image of molecule

p-(dimethylamino)benzylidene Meldrum's acid
0E Parameter: -12.76
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

p-(dimethylamino)benzylidenemalononitril
0E Parameter: -13.30
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

p-(methoxy)benzylidene Meldrum's acid
0E Parameter: -10.28
***J. Org. Chem. 2008, 73, 2738-2745
DOI: 10.1021/jo702590s
image of molecule

p-(methoxy)benzylidenemalononitril
0E Parameter: -10.80
***J. Org. Chem. 2003, 68, 6880-6886
DOI: 10.1021/jo0344182
image of molecule

tert-butyl prop-2-enoate (in DMSO)
DMSOE Parameter: -20.22
***J. Am. Chem. Soc. 2017, 139, 13318-13329
DOI: 10.1021/jacs.7b05106
image of molecule

tol(t-Bu)2QM
0E Parameter: -15.83
****Angew. Chem. Int. Ed. 2002, 41, 91-95
DOI: 10.1002/1521-3773(20020104)41:1<91::AID-ANIE91>3.0.CO;2-P