Mayr's Database of Reactivity Parameters

butanal (in DMSO)

Information panel

Name butanal (in DMSO)
Structure
Molecule class Electrophiles » C-Electrophiles » Aldehydes
SMILES CCCC=O
Molecular formula C4H8O
Quality -
Parameters
Comment

The reported E = –18.72 holds for the gross rate constant of the reversible attack of the S-ylide (4-NC-C6H4)CH=SMe2 at ArCHO (rate-determining epoxide ring closure).

Solvent DMSO
Reference J. Am. Chem. Soc. 2011, 133, 8240-8251
10.1021/ja200820m