Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
buta-1,3-diene   |
dichloromethane | N Param.: -0.87 sN Param.: 1.00 |
 |
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
9,10-dihydroanthracene  |
dichloromethane | N Param.: -0.86 sN Param.: 0.92 |
|
J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
2-(trimethylsilyl)thiophene  |
dichloromethane | N Param.: -0.80 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(2-([1,1'-biphenyl]-4-yl)ethyl)trimethylstannane  |
1,2-dichloroethane | N Param.: -0.80 sN Param.: 1.10 |
 |
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)5(PPh3)  |
dichloromethane | N Param.: -0.76 sN Param.: 0.90 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(E,E)-2,5-heptadiene  |
dichloromethane | N Param.: -0.74 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
4-methyl-2,5-heptadiene  |
dichloromethane | N Param.: -0.73 sN Param.: 0.97 |
|
J. Am. Chem. Soc. 2002, 124, 4076-4083 10.1021/ja0121538 |
diethylmercury (in MeCN)  |
MeCN | N Param.: -0.70 sN Param.: 1.10 |
|
Chem. Eur. J. 2013, 19, 249-263 10.1002/chem.201202839 |
1-(p-tolyl)-1-(trimethylsilyl)ethene  |
dichloromethane | N Param.: -0.65 sN Param.: 1.59 |
|
Chem. Eur. J. 2014, 20, 1103-1110 10.1002/chem.201303215 |
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane (in CH2Cl2)  |
dichloromethane | N Param.: -0.64 sN Param.: 1.10 |
|
J. Am. Chem. Soc. 2017, 139, 15324-15327 10.1021/jacs.7b10240 |