Mayr's Database of Reactivity Parameters

Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
3,5-dinitrobenzoate (in acetone)
*
 acetone

N  Param.: 18.80

sN Param.: 0.62		 ** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 90A10W)
*
 aq acetone

N  Param.: 12.71

sN Param.: 0.68		 *** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
acetate (in 80A20W)
*
 aq acetone

N  Param.: 12.50

sN Param.: 0.60		 ** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
benzoate (in 90AN10W)
*
 aq MeCN

N  Param.: 11.30

sN Param.: 0.72		 ** J. Am. Chem. Soc. 2008, 130, 3012-3022
10.1021/ja0765464
2-(1-azidovinyl)naphthalene (in Cyrene)
C12H9N3 *
 Cyrene (TM)

N  Param.: 6.00

sN Param.: 0.90		 *** Chem. Commun. 2026, 62, 5041-5045
10.1039/d6cc00190d
toluene
C7H8 *
 dichloromethane

N  Param.: -4.36

sN Param.: 1.77		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
m-xylene
C8H10 *
 dichloromethane

N  Param.: -3.57

sN Param.: 2.08		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(E)-propenylbenzene
C9H10 *
 dichloromethane

N  Param.: -0.49

sN Param.: 1.18		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-methylthiophene
C5H6S *
 dichloromethane

N  Param.: 1.35

sN Param.: 0.99		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
styrene
C8H8 *
 dichloromethane

N  Param.: 0.78

sN Param.: 0.95		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y