Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
2-methyl-but-2-ene
C5H10 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.17
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2,3-dimethyl-but-1-ene
C6H12 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.00
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(Z)-penta-1,3-diene
C5H8 *
dichloromethane

N  Param.: 0.66

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
cyclohexa-1,3-diene
C6H8 *
dichloromethane

N  Param.: 0.67

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
(1S)-(-)-alpha-pinene
C10H16 *
dichloromethane

N  Param.: 0.68

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4,6-trimethylstyrene
C11H14 *
dichloromethane

N  Param.: 0.68

sN Param.: 1.09
*** Macromolecules 2005, 38, 33-40
10.1021/ma048389o
styrene
C8H8 *
dichloromethane

N  Param.: 0.78

sN Param.: 0.95
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2,4,4-trimethyl-pent-1-ene
C8H16 *
dichloromethane

N  Param.: 0.79

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
chlorodimethylsilane
C2H7ClSi *
dichloromethane

N  Param.: 0.79

sN Param.: 0.73
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(chloromethyl)dimethylsilane
C3H9ClSi *
dichloromethane

N  Param.: 0.80

sN Param.: 0.73
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839