Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
tris(4-(dimethylamino)phenyl)methane (in MeCN)
C25H31N3 *
MeCN

N  Param.: -3.30

sN Param.: 0.82
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,2-dihydronaphthalene (in MeCN)
C10H10 *
MeCN

N  Param.: -3.30

sN Param.: 1.00
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dichloro(methyl)silane
*
dichloromethane

N  Param.: -3.20

sN Param.: 0.73
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilepane
*
dichloromethane

N  Param.: -3.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
3-methyl-1,4-pentadiene
C6H10 *
dichloromethane

N  Param.: -3.08

sN Param.: 0.97
* J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
2,4,5-trimethyl-1,3-dioxolane (anti)
*
dichloromethane

N  Param.: -3.00

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-pentadiene
C5H8 *
dichloromethane

N  Param.: -2.99

sN Param.: 0.97
* J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
3,3,3-trifluoro-2-(trimethylsiloxy)propene
*
dichloromethane

N  Param.: -2.94

sN Param.: 1.11
*** Org. Lett. 2012, 14, 3990-3993
10.1021/ol301766w
2-ethyl-4,5-dimethyl-1,3-dioxolane (anti)
*
dichloromethane

N  Param.: -2.90

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-dioxolane
C3H6O2 *
dichloromethane

N  Param.: -2.86

sN Param.: 0.80
*** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839