Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
1-(trimethylsiloxy)buta-1,3-diene   |
dichloromethane | N Param.: 4.60 sN Param.: 0.90 |
 |
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
1-(trimethylsiloxy)cycloheptene  |
dichloromethane | N Param.: 6.62 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
1-(trimethylsiloxy)cyclooctene  |
dichloromethane | N Param.: 6.77 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
Z-3-(trimethylsiloxy)pent-2-ene  |
dichloromethane | N Param.: 5.58 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
2-(trimethylsiloxy)furan  |
dichloromethane | N Param.: 7.22 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
3-(trimethylsilyl)cyclopentene  |
dichloromethane | N Param.: 1.77 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
3-(trihexylsilyl)cyclopentene  |
dichloromethane | N Param.: 1.98 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(2-methylallyl)trichlorosilane  |
dichloromethane | N Param.: -0.57 sN Param.: 0.95 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
allyltriphenylgermane  |
dichloromethane | N Param.: 1.20 sN Param.: 0.90 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
prenyl-tributylstannane  |
dichloromethane | N Param.: 4.74 sN Param.: 1.15 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(2-methylallyl)triphenylstannane  |
dichloromethane | N Param.: 5.13 sN Param.: 0.90 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(2-methylallyl)benzene  |
dichloromethane | N Param.: 0.25 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
alpha-methylstyrene  |
dichloromethane | N Param.: 2.35 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
2-cyclopropylpropene  |
dichloromethane | N Param.: 2.60 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(Z)-phenylpropene  |
dichloromethane | N Param.: -1.07 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
cyclopentene  |
dichloromethane | N Param.: -1.55 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(1S)-(-)-alpha-pinene  |
dichloromethane | N Param.: 0.68 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
(E)-but-2-ene  |
dichloromethane | N Param.: -2.45 sN Param.: 1.10 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
ethyl-vinylether  |
dichloromethane | N Param.: 3.92 sN Param.: 0.90 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
isobutylenyl-ethylether  |
dichloromethane | N Param.: 4.23 sN Param.: 1.00 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
anion of diethyl methylmalonate (in water)  |
water | N Param.: 17.68 sN Param.: 0.50 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
thiocyanate (in MeCN)  |
MeCN | N Param.: 12.13 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2003, 125, 14126-14132 10.1021/ja037317u |
chloride (in MeOH)  |
MeOH | N Param.: 12.90 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50/50 MeOH/MeCN)  |
MeOH-MeCN mix | N Param.: 14.10 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in EtOH)  |
EtOH | N Param.: 14.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 80% aq EtOH)  |
water-EtOH mix | N Param.: 13.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50% aq EtOH)  |
water-EtOH mix | N Param.: 11.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in H2O)  |
water | N Param.: 10.10 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 40% aq MeCN)  |
water-MeCN mix | N Param.: 11.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 50% aq MeCN)  |
water-MeCN mix | N Param.: 12.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 60% aq MeCN)  |
water-MeCN mix | N Param.: 12.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in 80% aq MeCN)  |
water-MeCN mix | N Param.: 13.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in CF3CH2OH)  |
TFE | N Param.: 10.30 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
chloride (in hexafluoroisopropanol)  |
HFIP | N Param.: 8.00 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 80% aq EtOH)  |
water-EtOH mix | N Param.: 14.50 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 50% aq EtOH)  |
water-EtOH mix | N Param.: 13.60 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in H2O)  |
water | N Param.: 11.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 20% aq MeCN)  |
water-MeCN mix | N Param.: 12.20 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 40% aq MeCN)  |
water-MeCN mix | N Param.: 12.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in 50% aq MeCN)  |
water-MeCN mix | N Param.: 13.80 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
bromide (in CF3CH2OH)  |
TFE | N Param.: 11.70 sN Param.: 0.60 |
|
J. Am. Chem. Soc. 2005, 127, 2641-2649 10.1021/ja045562n |
2-(tris(pentafluorophenyl)siloxy)-propene  |
dichloromethane | N Param.: 0.58 sN Param.: 0.91 |
|
Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 |
1-(tris(pentafluorophenyl)siloxy)-cyclopentene  |
dichloromethane | N Param.: 1.38 sN Param.: 0.93 |
|
Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 |
4-chloropyridine (in CH2Cl2)  |
dichloromethane | N Param.: 11.70 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
4-chloropyridine (in H2O)  |
water | N Param.: 10.50 sN Param.: 0.73 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
pyridine (in CH2Cl2)  |
dichloromethane | N Param.: 12.90 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
4-methylpyridine (in CH2Cl2)  |
dichloromethane | N Param.: 13.70 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
4-methoxypyridine (in CH2Cl2)  |
dichloromethane | N Param.: 13.70 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
4-aminopyridine (in CH2Cl2)  |
dichloromethane | N Param.: 15.20 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |
4-(dimethylamino)pyridine (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 13.20 sN Param.: 0.67 |
|
Chem. Eur. J. 2007, 13, 336-345 10.1002/chem.200600941 |