Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
tetraethylstannane (in MeCN)
*
MeCN

N  Param.: -2.40

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylstannyl)propyl)germane (in MeCN)
*
MeCN

N  Param.: -2.40

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
4,5-dimethyl-1,3-dioxolane (anti)
*
dichloromethane

N  Param.: -2.40

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn)
*
dichloromethane

N  Param.: -2.40

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
bis(4-methoxyphenyl)methane (in CH2Cl2)
C15H16O2 *
dichloromethane

N  Param.: -2.11

sN Param.: 0.98
** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,1-dimethylsiletane
*
dichloromethane

N  Param.: -2.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1% water/99% HFIP (w/w)
*
water-HFIP mix

N  Param.: -1.93

sN Param.: 1.09
*** J. Phys. Org. Chem. 2013, 26, 59-63
10.1002/poc.3064
tetraethylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -1.90

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
triethoxysilane
C6H16O3Si *
dichloromethane

N  Param.: -1.80

sN Param.: 0.75
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-chlorophenethyl)trimethylstannane
*
1,2-dichloroethane

N  Param.: -1.80

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839