Mayr's Database of Reactivity Parameters

Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
tetra-sec.butylstannane (in 1,2-DCE)
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.15
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(phenethyl)stannane
*
1,2-dichloroethane

N  Param.: -1.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(Z)-phenylpropene
C9H10 *
dichloromethane

N  Param.: -1.07

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-propyl-1,3-dioxolane
C6H12O2 *
dichloromethane

N  Param.: -1.06

sN Param.: 0.81
*** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
thiophene
C4H4S *
dichloromethane

N  Param.: -1.01

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
tetramethylethylene
C6H12 *
dichloromethane

N  Param.: -1.00

sN Param.: 1.40
*** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
trimethyl(3-(trimethylplumbyl)propyl)germane (in MeCN)
*
MeCN

N  Param.: -1.00

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyldioxolane
C9H10O2 *
dichloromethane

N  Param.: -0.90

sN Param.: 0.80
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3(C5H4CO2Me)
*
dichloromethane

N  Param.: -0.90

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
3-propylcyclopentene
C8H14 *
dichloromethane

N  Param.: -0.88

sN Param.: 0.94
*** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538