Mayr's Database of Reactivity Parameters

C-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1-methylcyclohexene
C7H12 *
 dichloromethane

N  Param.: 0.08

sN Param.: 1.15		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-but-2-ene
C5H10 *
 dichloromethane

N  Param.: 0.65

sN Param.: 1.17		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methylpropene (isobutylene)
C4H8 *
 dichloromethane

N  Param.: 1.11

sN Param.: 0.98		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-methyl-4-vinyl-benzene
C9H10 *
 dichloromethane

N  Param.: 1.70

sN Param.: 1.06		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-methyl-buta-1,3-diene (isoprene)
C5H8 *
 dichloromethane

N  Param.: 1.10

sN Param.: 0.98		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allylchlorodimethylsilane
C5H11ClSi *
 dichloromethane

N  Param.: -0.57

sN Param.: 1.06		 ***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
trimethyl(prenyl)silane
C8H18Si *
 dichloromethane

N  Param.: 0.90

sN Param.: 1.17		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(2-methylallyl)triphenylgermane
C22H22Ge *
 dichloromethane

N  Param.: 4.67

sN Param.: 0.81		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
allyl-tert.butyl-dimethylsilane
C9H20Si *
 dichloromethane

N  Param.: 1.80

sN Param.: 0.95		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
allyltriethylsilane
C9H20Si *
 dichloromethane

N  Param.: 1.93

sN Param.: 0.95		 * Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c