Mayr's Database of Reactivity Parameters

C-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
2-(trimethylsilyl)propene
C6H14Si *
dichloromethane

N  Param.: -1.46

sN Param.: 1.05
*** Chem. Eur. J. 2014, 20, 1103-1110
10.1002/chem.201303215
dimethyl diazomalonate
C5H6N2O4 *
dichloromethane

N  Param.: -1.24

sN Param.: 0.81
*** J. Am. Chem. Soc. 2023, 145, 7416-7434
10.1021/jacs.2c13872
anisole
C7H8O *
dichloromethane

N  Param.: -1.18

sN Param.: 1.20
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
alpha-(trimethylsilyl)styrene
C11H16Si *
dichloromethane

N  Param.: -1.13

sN Param.: 1.46
*** Chem. Eur. J. 2014, 20, 1103-1110
10.1002/chem.201303215
4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6
*
dichloromethane

N  Param.: -1.11

sN Param.: 0.92
*** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(Z)-phenylpropene
C9H10 *
dichloromethane

N  Param.: -1.07

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
thiophene
C4H4S *
dichloromethane

N  Param.: -1.01

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
tetramethylethylene
C6H12 *
dichloromethane

N  Param.: -1.00

sN Param.: 1.40
*** Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
buta-1,3-diene
C4H6 *
dichloromethane

N  Param.: -0.87

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-(trimethylsilyl)thiophene
C7H12SSi *
dichloromethane

N  Param.: -0.80

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c