Mayr's Database of Reactivity Parameters

C-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
2,5-dimethyl-hexa-1,5-diene
C8H14 *
dichloromethane

N  Param.: 1.14

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
methylenecyclohexane
C7H12 *
dichloromethane

N  Param.: 1.16

sN Param.: 1.04
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
(E,E)-hexa-2,4-diene
C6H10 *
dichloromethane

N  Param.: 1.17

sN Param.: 1.10
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,3-dimethyl-buta-1,3-diene
C6H10 *
dichloromethane

N  Param.: 1.17

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
1-methylcyclopentene
C6H10 *
dichloromethane

N  Param.: 1.18

sN Param.: 1.17
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
allyltriphenylgermane
C21H20Ge *
dichloromethane

N  Param.: 1.20

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
furan
C4H4O *
dichloromethane

N  Param.: 1.33

sN Param.: 1.29
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2-phenyl-4-(trimethylsilyl)but-1-en-3-ynyl-Co2(CO)6
*
dichloromethane

N  Param.: 1.33

sN Param.: 0.90
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2-methylthiophene
C5H6S *
dichloromethane

N  Param.: 1.35

sN Param.: 0.99
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-(tris(pentafluorophenyl)siloxy)-cyclopentene
C23H7F15OSi *
dichloromethane

N  Param.: 1.38

sN Param.: 0.93
* Eur. J. Org. Chem. 2005, , 1760-1764
10.1002/ejoc.200400706