C-Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
toluene   |
dichloromethane | N Param.: -4.36 sN Param.: 1.77 |
 |
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
m-xylene  |
dichloromethane | N Param.: -3.57 sN Param.: 2.08 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(E)-propenylbenzene  |
dichloromethane | N Param.: -0.49 sN Param.: 1.18 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2-methylthiophene  |
dichloromethane | N Param.: 1.35 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
styrene  |
dichloromethane | N Param.: 0.78 sN Param.: 0.95 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1,3-dimethoxybenzene  |
dichloromethane | N Param.: 2.48 sN Param.: 1.09 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltrimethylsilane  |
dichloromethane | N Param.: 1.68 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
allyltriphenylstannane  |
dichloromethane | N Param.: 3.09 sN Param.: 0.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)trimethylsilane  |
dichloromethane | N Param.: 4.41 sN Param.: 0.96 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltributylstannane  |
dichloromethane | N Param.: 5.46 sN Param.: 0.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)tributylstannane  |
dichloromethane | N Param.: 7.48 sN Param.: 0.89 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
Danishefskys diene  |
dichloromethane | N Param.: 8.57 sN Param.: 0.84 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran  |
dichloromethane | N Param.: 10.61 sN Param.: 0.86 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
5-(trimethylsiloxy)-2,3-dihydrofuran  |
dichloromethane | N Param.: 12.56 sN Param.: 0.70 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
methylenecyclopentane  |
dichloromethane | N Param.: 2.82 sN Param.: 0.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methylfuran  |
dichloromethane | N Param.: 3.61 sN Param.: 1.11 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
N-methylpyrrole  |
dichloromethane | N Param.: 5.85 sN Param.: 1.03 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclohexene  |
dichloromethane | N Param.: 5.21 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-(trimethylsiloxy)propene  |
dichloromethane | N Param.: 5.41 sN Param.: 0.91 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenyl-1-(trimethylsiloxy)ethene  |
dichloromethane | N Param.: 6.22 sN Param.: 0.96 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(trimethylsiloxy)cyclopentene  |
dichloromethane | N Param.: 6.57 sN Param.: 0.93 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-phenoxy-1-(trimethylsiloxy)ethene  |
dichloromethane | N Param.: 8.23 sN Param.: 0.81 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-morpholino)cyclohexene  |
dichloromethane | N Param.: 11.40 sN Param.: 0.83 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-(N-piperidino)cyclohexene  |
dichloromethane | N Param.: 13.36 sN Param.: 0.81 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allyltriphenylsilane  |
dichloromethane | N Param.: -0.13 sN Param.: 1.21 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
methylenecyclohexane  |
dichloromethane | N Param.: 1.16 sN Param.: 1.04 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2-chloropropene  |
dichloromethane | N Param.: -3.65 sN Param.: 1.97 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
1-hexene  |
dichloromethane | N Param.: -2.77 sN Param.: 1.41 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
1-methylcyclohexene  |
dichloromethane | N Param.: 0.08 sN Param.: 1.15 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-but-2-ene  |
dichloromethane | N Param.: 0.65 sN Param.: 1.17 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methylpropene (isobutylene)  |
dichloromethane | N Param.: 1.11 sN Param.: 0.98 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
1-methyl-4-vinyl-benzene  |
dichloromethane | N Param.: 1.70 sN Param.: 1.06 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-buta-1,3-diene (isoprene)  |
dichloromethane | N Param.: 1.10 sN Param.: 0.98 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
allylchlorodimethylsilane  |
dichloromethane | N Param.: -0.57 sN Param.: 1.06 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
trimethyl(prenyl)silane  |
dichloromethane | N Param.: 0.90 sN Param.: 1.17 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
(2-methylallyl)triphenylgermane  |
dichloromethane | N Param.: 4.67 sN Param.: 0.81 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2,3,3-trimethyl-but-1-ene  |
dichloromethane | N Param.: 0.06 sN Param.: 1.07 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2,3-dimethyl-but-1-ene  |
dichloromethane | N Param.: 0.65 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2,4,4-trimethyl-pent-1-ene  |
dichloromethane | N Param.: 0.79 sN Param.: 1.07 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
furan  |
dichloromethane | N Param.: 1.33 sN Param.: 1.29 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
1-methoxy-2-methyl-1-(trimethylsiloxy)propene  |
dichloromethane | N Param.: 9.00 sN Param.: 0.98 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
2-methyl-1-(trimethylsiloxy)propen  |
dichloromethane | N Param.: 3.94 sN Param.: 1.00 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
norbornene  |
dichloromethane | N Param.: -0.25 sN Param.: 1.09 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
1-methylcyclopentene  |
dichloromethane | N Param.: 1.18 sN Param.: 1.17 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
2-methyl-pent-1-ene  |
dichloromethane | N Param.: 0.84 sN Param.: 1.06 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
n-butyl vinyl ether  |
dichloromethane | N Param.: 3.76 sN Param.: 0.91 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
1-butoxy-1-(trimethylsiloxy)ethene  |
dichloromethane | N Param.: 10.21 sN Param.: 0.82 |
|
Eur. J. Org. Chem. 2004, , 2791-2796 10.1002/ejoc.200400134 |
1-butoxy-1-(t-butyl-dimethylsiloxy)ethene  |
dichloromethane | N Param.: 10.32 sN Param.: 0.79 |
|
Eur. J. Org. Chem. 2004, , 2791-2796 10.1002/ejoc.200400134 |
1,1-bis(trimethylsiloxy)propene  |
dichloromethane | N Param.: 10.38 sN Param.: 0.87 |
|
Eur. J. Org. Chem. 2004, , 2791-2796 10.1002/ejoc.200400134 |
1-(triphenylsiloxy)cyclopentene  |
dichloromethane | N Param.: 5.76 sN Param.: 1.02 |
|
Eur. J. Org. Chem. 2005, , 1760-1764 10.1002/ejoc.200400706 |