C-Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
6-(4-dimethylamino-phenyl)fulvene   |
MeCN | N Param.: 6.72 sN Param.: 0.87 |
 |
Eur. J. Org. Chem. 2009, , 1202-1206 10.1002/ejoc.200801099 |
6-(julolidin-9-yl)fulvene  |
MeCN | N Param.: 7.79 sN Param.: 1.06 |
|
Eur. J. Org. Chem. 2009, , 1202-1206 10.1002/ejoc.200801099 |
Ph3P=CH-CO2Et  |
dichloromethane | N Param.: 12.79 sN Param.: 0.77 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CO2Et (in DMSO)  |
DMSO | N Param.: 12.21 sN Param.: 0.62 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=C(CH3)-CO2Et  |
dichloromethane | N Param.: 13.09 sN Param.: 0.73 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-CN  |
dichloromethane | N Param.: 12.29 sN Param.: 0.75 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph3P=CH-COPh  |
dichloromethane | N Param.: 9.54 sN Param.: 0.97 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
(EtO)2P(O)CH(-)CO2Et (in DMSO)  |
DMSO | N Param.: 19.23 sN Param.: 0.65 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
(EtO)2P(O)CH(-)CN (in DMSO)  |
DMSO | N Param.: 18.57 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph2P(O)CH(-)CO2Et (in DMSO)  |
DMSO | N Param.: 19.20 sN Param.: 0.69 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph2P(O)CH(-)CN (in DMSO)  |
DMSO | N Param.: 18.69 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
(4-Br-C6H4)-(CO)-CH=SMe2  |
dichloromethane | N Param.: 11.95 sN Param.: 0.76 |
|
Angew. Chem. Int. Ed. 2009, 48, 5034-5037 10.1002/anie.200900933 |
Me2S=CH-CO2Et (in DMSO)  |
DMSO | N Param.: 15.85 sN Param.: 0.61 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
Me2S=CH-CN (in DMSO)  |
DMSO | N Param.: 16.23 sN Param.: 0.60 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
MeSO2-CH-CO2Et (in DMSO)  |
DMSO | N Param.: 18.00 sN Param.: 0.66 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
MeSO-CH-CO2Et (in DMSO)  |
DMSO | N Param.: 20.61 sN Param.: 0.64 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
(cyclohexen-1-yl)prolinate (in MeCN)  |
MeCN | N Param.: 18.86 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2010, 49, 9526-9529 10.1002/anie.201004344 |
1-(N-pyrrolidino)cyclohexene (in MeCN)  |
MeCN | N Param.: 16.42 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2010, 49, 9526-9529 10.1002/anie.201004344 |
methyl (cyclohexen-1-yl)prolinate (in MeCN)  |
MeCN | N Param.: 14.96 sN Param.: 0.68 |
|
Angew. Chem. Int. Ed. 2010, 49, 9526-9529 10.1002/anie.201004344 |
(4-Br-C6H4)-(CO)-CH=SMe2 (in DMSO)  |
DMSO | N Param.: 13.78 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
(C6H5)-(CO)-CH=SMe2 (in DMSO)  |
DMSO | N Param.: 13.95 sN Param.: 0.69 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
(4-MeO-C6H4)-(CO)-CH=SMe2 (in DMSO)  |
DMSO | N Param.: 14.48 sN Param.: 0.71 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
(4-Me2N-C6H4)-(CO)-CH=SMe2 (in DMSO)  |
DMSO | N Param.: 15.68 sN Param.: 0.65 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
Me2S=CH(p-NO2-C6H4) (in DMSO)  |
DMSO | N Param.: 18.42 sN Param.: 0.65 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
Me2S=CH(4-CN-C6H4) (in DMSO)  |
DMSO | N Param.: 21.07 sN Param.: 0.68 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
Me2S(O)=CH2 (in DMSO)  |
DMSO | N Param.: 21.29 sN Param.: 0.47 |
|
J. Am. Chem. Soc. 2010, 132, 17894-17900 10.1021/ja1084749 |
allyltris(trimethylsilyl)silane  |
dichloromethane | N Param.: 1.95 sN Param.: 0.98 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
(2-methylallyl)tris(trimethylsilyl)silane  |
dichloromethane | N Param.: 4.63 sN Param.: 0.87 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
2-(tris(trimethylsilyl)siloxy)propene  |
dichloromethane | N Param.: 6.04 sN Param.: 0.82 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
1-(tris(trimethylsilyl)siloxy)cyclohexene  |
dichloromethane | N Param.: 5.07 sN Param.: 0.91 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
(tris(trimethylsilyl)siloxy)ethene  |
dichloromethane | N Param.: 4.01 sN Param.: 0.83 |
|
Org. Lett. 2010, 12, 5206-5209 10.1021/ol102220e |
1,3-dimesityl-1H-imidazol-3-ium-2-ide (in THF)  |
THF | N Param.: 21.72 sN Param.: 0.45 |
|
Angew. Chem. Int. Ed. 2011, 50, 6915-6919 10.1002/anie.201102435 |
1,3-dimesityl-4,5-dihydro-1H-imidazol-3-ium-2-ide (in THF)  |
THF | N Param.: 23.35 sN Param.: 0.40 |
|
Angew. Chem. Int. Ed. 2011, 50, 6915-6919 10.1002/anie.201102435 |
1,3,4-triphenyl-1H-1,2,4-triazol-4-ium-5-ide (in THF)  |
THF | N Param.: 14.07 sN Param.: 0.84 |
|
Angew. Chem. Int. Ed. 2011, 50, 6915-6919 10.1002/anie.201102435 |
1-(N-piperidino)cyclohexene (in MeCN)  |
MeCN | N Param.: 14.02 sN Param.: 0.76 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
5-(trimethylsiloxy)-2,3-dihydrofuran (in MeCN)  |
MeCN | N Param.: 12.34 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran (in MeCN)  |
MeCN | N Param.: 10.52 sN Param.: 0.78 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
1-methoxy-2-methyl-1-(trimethylsiloxy)propene (in MeCN)  |
MeCN | N Param.: 9.11 sN Param.: 0.88 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
(5-methyl-furan-2-yl) pinacol boronate  |
MeCN | N Param.: 2.90 sN Param.: 0.98 |
|
Chem. Sci. 2012, 3, 878-882 10.1039/c2sc00883a |
(5-methyl-furan-2-yl) MDA boronate  |
MeCN | N Param.: 6.38 sN Param.: 0.86 |
|
Chem. Sci. 2012, 3, 878-882 10.1039/c2sc00883a |
(5-methyl-furan-2-yl) trifluoroborate  |
MeCN | N Param.: 7.66 sN Param.: 1.04 |
|
Chem. Sci. 2012, 3, 878-882 10.1039/c2sc00883a |
tetrakis(5-methyl-furan-2-yl)borate  |
MeCN | N Param.: 9.09 sN Param.: 1.12 |
|
Chem. Sci. 2012, 3, 878-882 10.1039/c2sc00883a |
(5-methyl-furan-2-yl)(1,1,1-tris(methoxy)ethane)borate  |
MeCN | N Param.: 12.55 sN Param.: 0.92 |
|
Chem. Sci. 2012, 3, 878-882 10.1039/c2sc00883a |
N-(1-phenylvinyl)acetamide  |
MeCN | N Param.: 5.73 sN Param.: 0.97 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
N-(1-(4-methoxyphenyl)vinyl)acetamide  |
MeCN | N Param.: 7.06 sN Param.: 0.85 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
N-(1-(4-chlorophenyl)vinyl)acetamide  |
MeCN | N Param.: 5.60 sN Param.: 1.00 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
benzyl (1-phenylvinyl)carbamate  |
MeCN | N Param.: 6.21 sN Param.: 0.87 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
N-(1-(naphthalen-2-yl)vinyl)acetamide  |
MeCN | N Param.: 6.28 sN Param.: 0.95 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
N-(3,4-dihydronaphthalen-1-yl)acetamide  |
MeCN | N Param.: 4.91 sN Param.: 0.87 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |
N-(cyclohex-1-en-1-yl)acetamide  |
MeCN | N Param.: 5.64 sN Param.: 0.79 |
|
Chem. Eur. J. 2012, 18, 5732-5740 10.1002/chem.201103519 |