C-Nucleophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
anion of (4-cyanophenyl)nitromethane (in DMSO)   |
DMSO | N Param.: 16.96 sN Param.: 0.73 |
 |
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-cyanophenyl)nitromethane (in water)  |
water | N Param.: 13.23 sN Param.: 0.52 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-nitrophenyl)nitromethane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 14.05 sN Param.: 0.72 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of (4-nitrophenyl)nitromethane (in DMSO)  |
DMSO | N Param.: 16.29 sN Param.: 0.75 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-nitrophenyl)nitromethane (in water)  |
water | N Param.: 13.58 sN Param.: 0.52 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of (4-NO2-C6H4)CH2SO2Ph (in DMSO)  |
DMSO | N Param.: 18.50 sN Param.: 0.75 |
|
Org. Biomol. Chem. 2008, 6, 3052-3058 10.1039/b805604h |
anion of (4-NO2-C6H4)CH2SO2Ph (in MeCN)  |
MeCN | N Param.: 19.90 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of (benzylsulfonyl)benzene (in DMSO)  |
DMSO | N Param.: 25.77 sN Param.: 0.56 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of (phenylmethylenedisulfonyl)dibenzene (in DMSO)  |
DMSO | N Param.: 15.07 sN Param.: 0.79 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 1,2,3-triphenylpropane-1,3-dione (in DMSO)  |
DMSO | N Param.: 14.99 sN Param.: 0.83 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 1,2-diphenylethanone (in DMSO)  |
DMSO | N Param.: 23.15 sN Param.: 0.60 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 1,3-diphenylpropane-1,3-dione (in DMSO)  |
DMSO | N Param.: 17.46 sN Param.: 0.65 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 1-phenyl-2-(phenylsulfonyl)ethanone (in DMSO)  |
DMSO | N Param.: 17.19 sN Param.: 0.56 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 1-phenylbutane-1,3-dione (in DMSO)  |
DMSO | N Param.: 16.03 sN Param.: 0.86 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 1-phenylpropan-2-one (in DMSO)  |
DMSO | N Param.: 24.99 sN Param.: 0.60 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 2-(4-CN-C6H4)propionitrile (in DMSO)  |
DMSO | N Param.: 25.35 sN Param.: 0.56 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 2-(4-NO2-C6H4)propionitrile (in DMSO)  |
DMSO | N Param.: 19.61 sN Param.: 0.60 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 2-nitro-1-phenylethan-1-one (in DMSO)  |
DMSO | N Param.: 13.91 sN Param.: 0.76 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 2-nitropropane (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 12.20 sN Param.: 0.71 |
|
Eur. J. Org. Chem. 2006, , 2530-2537 10.1002/ejoc.200500769 |
anion of 2-nitropropane (in DMSO)  |
DMSO | N Param.: 20.61 sN Param.: 0.69 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of 2-nitropropane (in water)  |
water | N Param.: 10.69 sN Param.: 0.56 |
|
J. Org. Chem. 2004, 69, 7565-7576 10.1021/jo048773j |
anion of 2-phenyl-2-(phenylsulfonyl)acetonitrile (in DMSO)  |
DMSO | N Param.: 15.97 sN Param.: 0.72 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 2-phenyl-propionitrile (in DMSO)  |
DMSO | N Param.: 28.95 sN Param.: 0.58 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 2-phenylmalononitrile (in DMSO)  |
DMSO | N Param.: 15.58 sN Param.: 1.00 |
|
Eur. J. Org. Chem. 2017, , 1196-1202 10.1002/ejoc.201601513 |
anion of 3-methyl acetylacetone (in DMSO)  |
DMSO | N Param.: 18.38 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of 3-methyl acetylacetone (in water)  |
water | N Param.: 14.33 sN Param.: 0.69 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of 3-oxo-3-phenylpropanenitrile (in DMSO)  |
DMSO | N Param.: 16.55 sN Param.: 0.78 |
|
Chem. Eur. J. 2015, 21, 875-884 10.1002/chem.201404500 |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 20.72 sN Param.: 0.58 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 17.33 sN Param.: 0.74 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-(trifluoromethyl)benzyl trifluoromethyl sulfone (in MeCN)  |
MeCN | N Param.: 16.15 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 4-(trifluoromethyl)benzyl-CN (in DMSO)  |
DMSO | N Param.: 27.28 sN Param.: 0.50 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 19.49 sN Param.: 0.63 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 16.28 sN Param.: 0.75 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-cyanobenzyl trifluoromethyl sulfone (in MeCN)  |
MeCN | N Param.: 15.62 sN Param.: 0.99 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 4-cyanobenzyl-CN (in DMSO)  |
DMSO | N Param.: 25.11 sN Param.: 0.54 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 19.35 sN Param.: 0.67 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 18.24 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 14.49 sN Param.: 0.86 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl-CN (in DMSO)  |
DMSO | N Param.: 19.67 sN Param.: 0.68 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 4-nitrobenzyl-CN (in MeCN)  |
MeCN | N Param.: 20.10 sN Param.: 0.71 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 5-(p-anisyl) Meldrum's acid (in DMSO)  |
DMSO | N Param.: 12.35 sN Param.: 0.90 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of 5-phenyl Meldrum's acid (in DMSO)  |
DMSO | N Param.: 11.54 sN Param.: 0.95 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of acetylacetone (in DMSO)  |
DMSO | N Param.: 17.64 sN Param.: 0.73 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of acetylacetone (in water)  |
water | N Param.: 13.73 sN Param.: 0.64 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of benzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 18.67 sN Param.: 0.68 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of diethyl 2-(4-nitrophenyl)malonate (in DMSO)  |
DMSO | N Param.: 14.94 sN Param.: 0.96 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(acetyl)malonate (in DMSO)  |
DMSO | N Param.: 13.83 sN Param.: 0.84 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(benzoyl)malonate (in DMSO)  |
DMSO | N Param.: 13.63 sN Param.: 0.80 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(isopropyl)malonate (in DMSO)  |
DMSO | N Param.: 18.74 sN Param.: 0.71 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of diethyl 2-(p-anisyl)malonate (in DMSO)  |
DMSO | N Param.: 16.73 sN Param.: 0.91 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |