Mayr's Database of Reactivity Parameters

Alkyl, Alkenyl and Aryl Boron Compounds

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Alkyl, Alkenyl and Aryl Boron Compounds

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
lithium 2-benzyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C20H23BF3LiO2 *
 MeCN

N  Param.: 7.15

sN Param.: 0.77		 *** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 2-benzyl-4,4,5,5-tetramethyl-2-phenyl-1,3,2-dioxaborolan-2-uide (in MeCN)
C19H24BLiO2 *
 MeCN

N  Param.: 8.92

sN Param.: 0.70		 ** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 2-cyclopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C16H21BF3LiO2 *
 MeCN

N  Param.: 7.72

sN Param.: 0.75		 * Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 2-ethyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H21BF3LiO2 *
 MeCN

N  Param.: 7.68

sN Param.: 0.78		 *** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 2-isopropyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C16H23BF3LiO2 *
 MeCN

N  Param.: 6.63

sN Param.: 0.75		 * Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 4,4,5,5-tetramethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C21H25BF3LiO2 *
 MeCN

N  Param.: 8.56

sN Param.: 0.76		 *** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(1-phenylethyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C20H26BLiO2 *
 MeCN

N  Param.: 10.97

sN Param.: 0.63		 ** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H22BLiO2 *
 MeCN

N  Param.: 11.00

sN Param.: 0.57		 *** J. Am. Chem. Soc. 2022, 144, 16118-16130
10.1021/jacs.2c06493
lithium 5,5-dimethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborinan-2-uide (in MeCN)
C20H23BF3LiO2 *
 MeCN

N  Param.: 11.29

sN Param.: 0.76		 *** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium bis(5-methylthiophen-2-yl)pinacolborate
C16H22BLiO2S2 *
 MeCN

N  Param.: 7.67

sN Param.: 0.87		 ** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562