Mayr's Database of Reactivity Parameters

Alkyl, Alkenyl and Aryl Boron Compounds

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
potassium trifluoro(furan-3-yl)borate
C4H3BF3KO *
MeCN

N  Param.: 6.83

sN Param.: 0.93
*** J. Am. Chem. Soc. 2013, 135, 6317-6324
10.1021/ja4017655
potassium trifluoro(3-methoxy-thiophen-2-yl)borate
C5H5BF3KOS *
MeCN

N  Param.: 7.32

sN Param.: 0.90
*** J. Am. Chem. Soc. 2013, 135, 6317-6324
10.1021/ja4017655
lithium (5-methylthiophen-2-yl)(3,5-bis(trifluoromethyl)phenyl)glycolborate
C15H12BF6LiO2S *
MeCN

N  Param.: 11.23

sN Param.: 0.77
*** Angew. Chem. Int. Ed. 2015, 54, 2780-2783
10.1002/anie.201410562
lithium 2-benzyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C20H23BF3LiO2 *
MeCN

N  Param.: 7.15

sN Param.: 0.77
*** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 4,4,5,5-tetramethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C21H25BF3LiO2 *
MeCN

N  Param.: 8.56

sN Param.: 0.76
*** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 2-ethyl-4,4,5,5-tetramethyl-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H21BF3LiO2 *
MeCN

N  Param.: 7.68

sN Param.: 0.78
*** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 5,5-dimethyl-2-(1-phenylethyl)-2-(4-(trifluoromethyl)phenyl)-1,3,2-dioxaborinan-2-uide (in MeCN)
C20H23BF3LiO2 *
MeCN

N  Param.: 11.29

sN Param.: 0.76
*** Org. Lett. 2015, 17, 2614-2617
10.1021/acs.orglett.[...]
lithium 4,4,5,5-tetramethyl-2-phenyl-2-(prop-1-en-2-yl)-1,3,2-dioxaborolan-2-uide (in MeCN)
C15H22BLiO2 *
MeCN

N  Param.: 11.00

sN Param.: 0.57
*** J. Am. Chem. Soc. 2022, 144, 16118-16130
10.1021/jacs.2c06493