Mayr's Database of Reactivity Parameters

Enol Ethers

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Enol Ethers

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
Danishefskys diene
C8H16O2Si *
 dichloromethane

N  Param.: 8.57

sN Param.: 0.84		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-(trimethylsiloxy)-5,6-dihydro-4H-pyran
C8H16O2Si *
 dichloromethane

N  Param.: 10.61

sN Param.: 0.86		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
5-(trimethylsiloxy)-2,3-dihydrofuran
C7H14O2Si *
 dichloromethane

N  Param.: 12.56

sN Param.: 0.70		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-(trimethylsiloxy)cyclohexene
C9H18OSi *
 dichloromethane

N  Param.: 5.21

sN Param.: 1.00		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-(trimethylsiloxy)propene
C6H14OSi *
 dichloromethane

N  Param.: 5.41

sN Param.: 0.91		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-phenyl-1-(trimethylsiloxy)ethene
C11H16OSi *
 dichloromethane

N  Param.: 6.22

sN Param.: 0.96		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-(trimethylsiloxy)cyclopentene
C8H16OSi *
 dichloromethane

N  Param.: 6.57

sN Param.: 0.93		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-phenoxy-1-(trimethylsiloxy)ethene
C11H16O2Si *
 dichloromethane

N  Param.: 8.23

sN Param.: 0.81		 ***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
(triisopropylsiloxy)ethene
C11H24OSi *
 dichloromethane

N  Param.: 3.44

sN Param.: 0.94		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
2-(triisopropylsiloxy)propene
C12H26OSi *
 dichloromethane

N  Param.: 5.38

sN Param.: 0.85		 ** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y