Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
C7H7+-Fe(CO)3   |
E Param.: -3.49, Deviation: ±0.17 |
 |
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C7H9+-Fe(CO)3  |
E Param.: -9.21, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H7+-Fe(CO)3  |
E Param.: -7.76, Deviation: ±0.31 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
C6H6OMe+-Fe(CO)3  |
E Param.: -8.94, Deviation: ±0.13 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
benzaldehyde-boron trichloride complex  |
E Param.: 1.12, Deviation: ±0.24 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
4-chlorobenzaldehyde-boron trichloride complex  |
E Param.: 1.44, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
propyn-1-ylium-Co2(CO)6  |
E Param.: -0.84, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-proyn-ylium-Co2(CO)6  |
E Param.: -0.97, Deviation: ±0.08 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-phenylpropyn-1-ylium-Co2(CO)6  |
E Param.: -1.58, Deviation: ±0.58 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6  |
E Param.: -1.60, Deviation: ±0.34 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)  |
E Param.: -6.19, Deviation: ±0.44 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
Pd-allyl cation  |
E Param.: -10.11, Deviation: ±0.96 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,3-diphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: 1.07, Deviation: ±0.30 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3  |
E Param.: -0.25, Deviation: ±0.20 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
dicarbonyl(cyclopentadienyl)propene-iron(II)  |
E Param.: -11.20 |
|
Helv. Chim. Acta 2005, 88, 1754-1768 10.1002/hlca.200590137 |
|
bh6a  |
E Param.: -18.60 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6f  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6i  |
E Param.: -19.10 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh6j  |
E Param.: -17.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6k  |
E Param.: -18.20 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6l  |
E Param.: -18.90 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
bh 6m  |
E Param.: -17.30 |
|
Chem. Eur. J. 2010, 16, 1365-1371 10.1002/chem.200902487 |
|
ani(t-Bu)2QM  |
E Param.: -16.11 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
dma(t-Bu)2QM  |
E Param.: -17.29 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
cumyl cation  |
E Param.: 5.74 |
|
Macromolecules 2010, 43, 1719-1723 10.1021/ma9024569 |
|
(4-CF3)2-tritylium ion  |
E Param.: 2.28 |
 |
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-Cl)3-tritylium ion  |
E Param.: 1.99 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-CF3)-tritylium ion  |
E Param.: 1.33 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-Cl)-tritylium ion  |
E Param.: 1.06 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(3-CF3)-tritylium ion  |
E Param.: 1.18 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-Me)-tritylium ion  |
E Param.: -0.13 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-Me)2-tritylium ion  |
E Param.: -0.70 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-Me)3-tritylium ion  |
E Param.: -1.21 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-MeO,3-OMe)-tritylium ion  |
E Param.: -1.62 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-OMe,3-Me)-tritylium ion  |
E Param.: -1.84 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-MeO)-tritylium ion  |
E Param.: -1.59 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(4-MeO,4-Me)-tritylium ion  |
E Param.: -2.13 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-MeO)2-tritylium ion  |
E Param.: -3.04 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-MeO)3-tritylium ion  |
E Param.: -4.35 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-NMe2)-tritylium ion  |
E Param.: -7.93 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-NMe2)2-tritylium ion (= Malachite green)  |
E Param.: -10.29 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-NMe2)3-tritylium ion (= Crystal violet)  |
E Param.: -11.26 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
(4-F)-tritylium ion  |
E Param.: 0.35 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(4-F)2-tritylium ion  |
E Param.: 0.17 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(4-F)3-tritylium ion  |
E Param.: 0.05 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(3-F)-tritylium ion  |
E Param.: 1.01 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(3-F)2-tritylium ion  |
E Param.: 1.54 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(3-F)3-tritylium ion  |
E Param.: 2.07 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
(3-F)4-tritylium ion  |
E Param.: 2.54 |
|
Eur. J. Org. Chem. 2011, , 6470-6475 10.1002/ejoc.201100910 |
|
diarylallylium ion (3,3-F2)2  |
E Param.: 6.11 |
|
J. Org. Chem. 2011, 76, 9391-9408 10.1021/jo201668w |