Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
(thq)2CH+		E Param.: -8.22	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
(tol)2CH+		E Param.: 3.63	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y
1,1,3-triphenylallylium ion		E Param.: 0.98, Deviation: ±0.20	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,1,3-triphenylpropyn-1-ylium-Cr(CO)3		E Param.: -0.25, Deviation: ±0.20	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,1,3-tris(4-(dimethylamino)phenyl)allylium ion		E Param.: -9.84, Deviation: ±0.21	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,1-bis(4-dimethylaminophenyl)-3-phenylallylium ion		E Param.: -8.97, Deviation: ±0.32	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,1-dianisyl-3-phenylallylium ion		E Param.: -2.67, Deviation: ±0.30	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,2-diaza-1,3-diene 1a	DMSO	E Param.: -13.28	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1b	DMSO	E Param.: -13.90	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1c	DMSO	E Param.: -14.91	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1d	DMSO	E Param.: -15.38	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1e	MeOH	E Param.: -14.90	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1f	MeOH	E Param.: -15.30	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,3,5-trinitrobenzene		E Param.: -13.19, Deviation: ±0.45	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
1,3-bis(2,4,6-trimethylphenyl)but-1-ylium ion		E Param.: 6.16	Macromolecules 2005, 38, 33-40 10.1021/ma048389o
1,3-diphenylpropyn-1-ylium-Cr(CO)3		E Param.: 1.07, Deviation: ±0.30	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,3-dithianylium ion		E Param.: -2.14, Deviation: ±0.07	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1,4-dioxaspiro[4.5]decan-8-one (in DMSO)	DMSO	E Param.: -18.20	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1-(4-chlorophenyl)cyclopent-2-enylium ion		E Param.: 3.20, Deviation: ±0.37	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1-(tert-butyl)-2-cinnamoyl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.80	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
1-methyl-3-((julolidin-9-yl)methylene)-3H-indol-1-ium ion		E Param.: -7.79	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methyl-3-(4-methylbenzylidene)-3H-indol-1-ium ion		E Param.: -2.19	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
1-methylpiperidin-4-one (in DMSO)	DMSO	E Param.: -18.40	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1-methylsulfanylpropan-2-one (in DMSO)	DMSO	E Param.: -15.60	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
1-phenyl-propyn-1-ylium-Co2(CO)5(PPh3)		E Param.: -6.19, Deviation: ±0.44	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1-phenyl-proyn-ylium-Co2(CO)6		E Param.: -0.97, Deviation: ±0.08	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1-phenylcyclopent-2-enylium ion		E Param.: 2.89, Deviation: ±0.25	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
1-phenylprop-2-en-1-one (in DMSO)	DMSO	E Param.: -15.25	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
2,2,4-trichloro-1(2H)-naphthalenone	MeCN	E Param.: -11.24	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one	MeCN	E Param.: -6.75	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
2,4-dinitrothiophene		E Param.: -12.33, Deviation: ±0.11	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
2,5-dichloroquinone (C-Cl)		E Param.: -16.11	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2,5-dichloroquinone (C-H)		E Param.: -12.28	J. Am. Chem. Soc. 2014, 136, 11499-11512 10.1021/ja505613b
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -11.68	Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295
2,6-di-tert-butyl-4-(methoxymethylene)cyclohexa-2,5-dien-1-one		E Param.: -15.10	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-ethylidenecyclohexa-2,5-dien-1-one		E Param.: -13.68	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dien-1-one		E Param.: -11.17	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert.butyl-4-(3,5-difluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.50	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(3-fluorobenzylidene)cyclohexa-2,5-dienone		E Param.: -15.03	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-di-tert.butyl-4-(4-nitrobenzylidene)cyclohexa-2,5-dienone		E Param.: -14.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -17.18	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethoxy-4-(4-methoxybenzylidene)cyclohexa-2,5-dienone		E Param.: -16.38	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-dimethyl-4-(4-(dimethylamino)benzylidene)cyclohexa-2,5-dienone		E Param.: -16.36	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2,6-diphenyl-4-benzylidenecyclohexa-2,5-dienone		E Param.: -11.87	Eur. J. Org. Chem. 2009, , 3203-3211 10.1002/ejoc.200900299
2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetonitrile		E Param.: -11.88	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2-(4-methoxybenzylidene)-1,3-dithiane 1,1,3,3-tetraoxide	DMSO	E Param.: -14.55	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
2-(4-methoxybenzylidene)benzo[d][1,3]dithiole 1,1,3,3-tetraoxide	DMSO	E Param.: -13.02	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
2-(4-methoxyphenyl)chromenylium ion		E Param.: -4.95, Deviation: ±0.06	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2-(p-(dimethylamino)benzylidene)-indan-1,3-dione		E Param.: -13.56	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
2-(p-methoxybenzylidene)-indan-1,3-dione		E Param.: -11.32	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e