Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
E)-2,6-di-tert-butyl-4-(3-(4-chlorophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.84	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
(E)-2,6-di-tert-butyl-4-(3-(4-nitrophenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -16.25	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
(E)-2,6-di-tert-butyl-4-(3-(4-methoxyphenyl)allylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -17.42	Org. Lett. 2020, 22, 2182-2186 10.1021/acs.orglett.[...]
2,6-di-tert-butyl-4-(2,2,2-trifluoroethylidene)cyclohexa-2,5-dien-1-one	DMSO	E Param.: -11.68	Eur. J. Org. Chem. 2020, , 3812-3817 10.1002/ejoc.202000295
3-nitro-1-tosyl-1H-indole		E Param.: -14.87	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
phenyl isocyanate	MeCN	E Param.: -15.38	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
p-tosyl isocyanate	MeCN	E Param.: -7.69	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
phenyl isothiocyanate	DMSO	E Param.: -18.15	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
p-nitrophenyl isothiocyanate	DMSO	E Param.: -15.89	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
diphenylcarbodiimide	DMSO	E Param.: -20.14	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
carbon disulfide	DMSO	E Param.: -17.70	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
3,6-dinitro-1-tosyl-1H-indole		E Param.: -12.90	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
cycloheptenone	DMSO	E Param.: -22.00	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
methyl diazoacetate		E Param.: -18.50	Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376
dimethyl diazomalonate		E Param.: -18.20	Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376
(p-nitrophenyl)diazomethane		E Param.: -18.30	Chem. Eur. J. 2022, 28, e202201376 10.1002/chem.202201376
Umemoto I (triflate)		E Param.: -13.08	Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085
Umemoto I (tetrafluoroborate)		E Param.: -13.39	Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085
Umemoto II (triflate)		E Param.: -12.80	Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085
(E)-6-(4-nitrobenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -13.15	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(4-(trifluoromethyl)benzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -13.54	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(3-fluorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -14.00	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(4-chlorobenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -13.99	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-benzylidenebenzo[d][1,3]dioxol-5(6H)-one		E Param.: -14.47	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(4-methylbenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -14.85	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(4-methoxybenzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.20	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(4-(dimethylamino)benzylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -16.07	Chem. Eur. J. 2025, 31, e202403785 10.1002/chem.202403785
(E)-6-(furan-2-ylmethylene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.73	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
(E)-6-((1-methyl-1H-pyrrol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -17.03	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
(E)-6-((1-methyl-1H-indol-2-yl)methylene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -15.55	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
(E)-6-((E)-3-phenylallylidene)benzo[d][1,3]dioxol-5(6H)-one		E Param.: -16.00	Org. Biomol. Chem. 2025, 23, 827-834 10.1039/D4OB01855A
2,6-di-tert-butyl-4-methylenecyclohexa-2,5-dien-1-one		E Param.: -11.17	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-(methoxymethylene)cyclohexa-2,5-dien-1-one		E Param.: -15.10	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetonitrile		E Param.: -11.88	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
ethyl 2-(3,5-di-tert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)acetate		E Param.: -12.01	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
2,6-di-tert-butyl-4-ethylidenecyclohexa-2,5-dien-1-one		E Param.: -13.68	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
4-benzylidene-2,6-di-tert-butylcyclohexa-2,5-dien-1-one		E Param.: -15.58	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
(E)-10-(4-methoxybenzylidene)phenanthren-9(10H)-one		E Param.: -15.93	J. Phys. Org. Chem. 2026, 39, e70061 10.1002/poc.70061
(E)-2-(4-methoxybenzylidene)acenaphthylen-1(2H)-one		E Param.: -18.72	J. Phys. Org. Chem. 2026, 39, e70061 10.1002/poc.70061
ani(Br)2QM		E Param.: -8.63	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
ani(Ph)2QM		E Param.: -12.18	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
dma(Ph)2QM		E Param.: -13.39	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
tol(t-Bu)2QM		E Param.: -15.83	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
ani(t-Bu)2QM		E Param.: -16.11	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
dma(t-Bu)2QM		E Param.: -17.29	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
jul(t-Bu)2QM		E Param.: -17.90	Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...]
benzhydrylium ion Ph2CH+		E Param.: 5.47	J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b
(pcp)2CH+		E Param.: 5.48	J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b
pfp(Ph)CH+		E Param.: 5.20	J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b
(fur)2CH+		E Param.: -1.36	J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y