Electrophiles
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
pfp(Ph)CH+   |
E Param.: 5.20 |
 |
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
Ph2C=C=N(+)Me2  |
E Param.: -1.90 |
 |
Synthesis 2025, 57, 3251-3262 10.1055/a-2649-1999 |
|
PhCH=N+(CH2)4 (in MeCN)  |
MeCN | E Param.: -9.35 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+(CH2)5 (in MeCN)  |
MeCN | E Param.: -9.60 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
PhCH=N+Me2 (in MeCN)  |
MeCN | E Param.: -9.27 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
phenyl isocyanate  |
MeCN | E Param.: -15.38 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
phenyl isothiocyanate  |
DMSO | E Param.: -18.15 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
pipN+=CH-CH-Ph  |
E Param.: -10.30 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
pop(Ph)CH+  |
E Param.: 2.90 |
|
J. Am. Chem. Soc. 2001, 123, 9500-9512 10.1021/ja010890y |
|
pop(tol)CH+  |
E Param.: 2.16, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
propyn-1-ylium-Co2(CO)6  |
E Param.: -0.84, Deviation: ±0.36 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
pTolCH=N+CH2 (in MeCN)  |
MeCN | E Param.: -9.64 |
|
J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x |
pyrN+=CH-CH-Ph  |
E Param.: -9.80 |
|
Angew. Chem. Int. Ed. 2008, 47, 8723-8726 10.1002/anie.200802889 |
|
Selectfluor  |
E Param.: -5.20 |
|
J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147 |
|
tert-butyl prop-2-enoate (in DMSO)  |
DMSO | E Param.: -20.22 |
|
J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106 |
thian-4-one (in DMSO)  |
DMSO | E Param.: -16.90 |
|
J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657 |
tol(Ph)CH+  |
E Param.: 4.43 |
|
J. Am. Chem. Soc. 2012, 134, 13902-13911 10.1021/ja306522b |
|
tol(t-Bu)2QM  |
E Param.: -15.83 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
|
tritylium ion (Ph3C+)  |
E Param.: 0.51 |
|
J. Am. Chem. Soc. 2003, 125, 286-295 10.1021/ja021010y |
|
tropylium ion  |
E Param.: -3.72, Deviation: ±0.03 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
Umemoto I (tetrafluoroborate)  |
E Param.: -13.39 |
|
Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 |
|
Umemoto I (triflate)  |
E Param.: -13.08 |
|
Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 |
|
Umemoto II (triflate)  |
E Param.: -12.80 |
|
Eur. J. Org. Chem. 2024, 27, e202400085 10.1002/ejoc.202400085 |
|
Vilsmeier ion  |
E Param.: -5.77 |
|
Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 3,5-difluorophenyl)  |
E Param.: -14.21 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = 4-(dimethylamino)phenyl)  |
E Param.: -14.46 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |
|
[(1,3-Diarylallyl)Pd(PPh3)2]+ (Aryl = Ph)  |
E Param.: -14.14 |
|
Organometallics 2012, 31, 2416-2424 10.1021/om3000357 |