Mayr's Database of Reactivity Parameters

Electrophiles

For reactivities of structurally related compounds go to: Electrophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
diethyl 4-methyl-benzylidene malonate
C15H18O4 *

E Param.: -21.11

 *** Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
cyclopentanone (in DMSO)
C5H8O *
 DMSO

E Param.: -21.00

 * J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
furan-2(5H)-one
C4H4O2 *
 DMSO

E Param.: -20.70

 *** Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
cyclopentenone
C5H6O *
 DMSO

E Param.: -20.60

 *** Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
diethyl benzylidene malonate
C14H16O4 *

E Param.: -20.55

 *** Chem. Eur. J. 2008, 14, 9675-9682
10.1002/chem.200801277
tert-butyl prop-2-enoate (in DMSO)
C7H12O2 *
 DMSO

E Param.: -20.22

 *** J. Am. Chem. Soc. 2017, 139, 13318-13329
10.1021/jacs.7b05106
diphenylcarbodiimide
C13H10N2 *
 DMSO

E Param.: -20.14

 *** J. Am. Chem. Soc. 2020, 142, 8383-8402
10.1021/jacs.0c01960
cyclohexanone (in DMSO)
C6H10O *
 DMSO

E Param.: -19.90

 * J. Am. Chem. Soc. 2018, 140, 5500-5515
10.1021/jacs.8b01657
3-methylenetetrahydropyran-2-one
C6H8O2 *
 DMSO

E Param.: -19.50

 *** Chem. Sci. 2021, 12, 4850-4865
10.1039/D0SC06628A
diethyl maleate
C8H12O4 *
 DMSO

E Param.: -19.49

 *** Eur. J. Org. Chem. 2014, , 2956-2963
10.1002/ejoc.201301779