Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
1,2-diaza-1,3-diene 1e	MeOH	E Param.: -14.90	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1f	MeOH	E Param.: -15.30	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
MacMillan-iminium ion (1st generation)	MeCN	E Param.: -7.37	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
2,3,4,5,6,6-hexachlorocyclohexa-2,4-dien-1-one	MeCN	E Param.: -6.75	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
5,7,7-trichloro-8(7H)-quinolinone	MeCN	E Param.: -10.48	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
2,2,4-trichloro-1(2H)-naphthalenone	MeCN	E Param.: -11.24	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
dibenzyl azodicarboxylate	MeCN	E Param.: -8.89	Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598
diethyl azodicarboxylate	MeCN	E Param.: -10.15	Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598
diisopropyl azodicarboxylate	MeCN	E Param.: -10.71	Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598
di-tert-butyl azodicarboxylate	MeCN	E Param.: -12.23	Chem. Eur. J. 2010, 16, 11670-11677 10.1002/chem.201001598
MacMillan-iminium ion (2nd generation)	MeCN	E Param.: -5.52	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
MacMillan-iminium ion (spiro)	MeCN	E Param.: -7.67	Angew. Chem. Int. Ed. 2011, 50, 9953-9956 10.1002/anie.201103683
PhCH=N+Me2 (in MeCN)	MeCN	E Param.: -9.27	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
pTolCH=N+CH2 (in MeCN)	MeCN	E Param.: -9.64	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-AniCH=N+Me2 (in MeCN)	MeCN	E Param.: -10.69	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)4 (in MeCN)	MeCN	E Param.: -9.35	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
PhCH=N+(CH2)5 (in MeCN)	MeCN	E Param.: -9.60	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
p-CF3-C6H4-CH=N+Me2 (in MeCN)	MeCN	E Param.: -8.34	J. Am. Chem. Soc. 2013, 135, 6579-6587 10.1021/ja401106x
2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ)	MeCN	E Param.: -3.66	J. Am. Chem. Soc. 2013, 135, 12377-12387 10.1021/ja405890d
NFSI	MeCN	E Param.: -8.44	J. Am. Chem. Soc. 2018, 140, 11474-11486 10.1021/jacs.8b07147
phenyl isocyanate	MeCN	E Param.: -15.38	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
p-tosyl isocyanate	MeCN	E Param.: -7.69	J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960
1,2-diaza-1,3-diene 1a	DMSO	E Param.: -13.28	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1b	DMSO	E Param.: -13.90	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1c	DMSO	E Param.: -14.91	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
1,2-diaza-1,3-diene 1d	DMSO	E Param.: -15.38	Chem. Eur. J. 2010, 16, 12008-12016 10.1002/chem.201000828
(E)-3-(4-nitro-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)	DMSO	E Param.: -17.33	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-3-(4-cyano-phenyl)-1-phenyl-prop-2-en-1-one (in DMSO)	DMSO	E Param.: -17.64	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-1,3-diphenylprop-2-en-1-one (in DMSO)	DMSO	E Param.: -19.39	J. Am. Chem. Soc. 2017, 139, 13318-13329 10.1021/jacs.7b05106
(E)-4-(4-nitrophenyl)but-3-en-2-one (in DSMO)	DMSO	E Param.: -19.36	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-4-methyl-1-(4-nitrophenyl)pent-1-en-3-one (in DMSO)	DMSO	E Param.: -19.17	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-4,4-dimethyl-1-(4-nitrophenyl)pent-1-en-3-one	DMSO	E Param.: -19.15	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-chloro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-methoxy-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
4-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
benzaldehyde (in DMSO)	DMSO	E Param.: -12.90	J. Am. Chem. Soc. 2018, 140, 5500-5515 10.1021/jacs.8b01657
hexanal (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
butanal (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
cinnamaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
p-nitro-cinnamaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-N-benzylidene-4-methylbenzenesulfonamide (in DMSO)	DMSO	E Param.: -11.50	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-N-(4-methoxybenzylidene)-4-methylbenzenesulfonamide (in DMSO)	DMSO	E Param.: -13.05	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-N-(4-(dimethylamino)benzylidene)-4-methylbenzenesulfonamide (in DMSO)	DMSO	E Param.: -15.09	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-tert-butyl benzylidenecarbamate (in DMSO)	DMSO	E Param.: -14.22	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(E)-N-benzylidene-P,P-diphenylphosphinic amide	DMSO	E Param.: -15.89	J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
(ethene-1,1-diyldisulfonyl)dibenzene	DMSO	E Param.: -7.50	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
(2-phenylethene-1,1-diyldisulfonyl)dibenzene	DMSO	E Param.: -12.93	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
(2-(4-methoxyphenyl)ethene-1,1-diyldisulfonyl)dibenzene	DMSO	E Param.: -13.88	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline	DMSO	E Param.: -16.53	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046