Electrophiles

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Name	Solvent	Reactivity Parameters	Reference (title or year)
2-benzylidene-indan-1,3-dione		E Param.: -10.11	Org. Biomol. Chem. 2007, 5, 3020-3026 10.1039/b708025e
2-benzylidenebenzo[d][1,3]dithiole 1,1,3,3-tetraoxide	DMSO	E Param.: -11.78	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
2-cinnamoyl-1,3-dimethyl-1H-imidazol-3-ium	DMSO	E Param.: -11.52	Angew. Chem. Int. Ed. 2012, 51, 5234-5238 10.1002/anie.201109042
2-cinnamoyl-1-(2,6-dimethoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -12.02	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-(4-methoxyphenyl)-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.79	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-1-mesityl-3-methyl-1H-imidazol-3-ium	DMSO	E Param.: -11.48	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-cinnamoyl-3-methyl-1-(perfluorophenyl)-1H-imidazol-3-ium	DMSO	E Param.: -10.09	Top. Catal. 2018, 61, 585-590 10.1007/s11244-018-0[...]
2-methylcyclohexenone	DMSO	E Param.: -27.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
2-methylcyclopentenone	DMSO	E Param.: -22.10	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
2-phenyl-1,3-dithianylium ion		E Param.: -6.43, Deviation: ±0.04	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2-phenyl-1,3-dithiolan-2-ylium ion		E Param.: -5.91, Deviation: ±0.33	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
2-phenylethene-1-sulfonyl fluoride	DMSO	E Param.: -16.63	Angew. Chem. Int. Ed. 2016, 55, 12664-12667 10.1002/anie.201601875
3,6-dinitro-1-tosyl-1H-indole		E Param.: -12.90	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
3-(4-(dimethylamino)benzylidene)-1-methyl-3H-indol-1-ium ion		E Param.: -6.26	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(4-methoxybenzylidene)-1-methyl-3H-indol-1-ium iom		E Param.: -3.02	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-(trimethylsilyl)propyn-1-ylium-Co2(CO)6		E Param.: -1.60, Deviation: ±0.34	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
3-benzylidene-1-methyl-3H-indol-1-ium ion		E Param.: -1.80	J. Org. Chem. 2015, 80, 8643-8656 10.1021/acs.joc.5b01298
3-chloro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-methoxy-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
3-methylcyclohexenone	DMSO	E Param.: -29.60	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylcyclopentenone	DMSO	E Param.: -28.90	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenedihydrofuranone	DMSO	E Param.: -19.40	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-methylenetetrahydropyran-2-one	DMSO	E Param.: -19.50	Chem. Sci. 2021, 12, 4850-4865 10.1039/D0SC06628A
3-nitro-1-tosyl-1H-indole		E Param.: -14.87	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
3-phenylpropyn-1-ylium-Co2(CO)6		E Param.: -1.58, Deviation: ±0.58	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
4,6-dinitrobenzofurazan		E Param.: -5.46, Deviation: ±0.36	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4,6-dinitrobenzofuroxan		E Param.: -5.06	J. Org. Chem. 2006, 71, 9088-9095 10.1021/jo0614339
4,6-dinitrotetrazolopyridine		E Param.: -4.67, Deviation: ±0.30	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-(2,2-bis(phenylsulfonyl)vinyl)-N,N-dimethylaniline	DMSO	E Param.: -16.53	Chem. Asian J. 2012, 7, 1401-1407 10.1002/asia.201101046
4-aza-6-nitrobenzofuroxan		E Param.: -5.86, Deviation: ±0.36	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-benzylidene-2,6-di-tert-butylcyclohexa-2,5-dien-1-one		E Param.: -15.58	Chem. Eur. J. 2025, 31, e202501224 10.1002/chem.202501224
4-bromo-3-nitro-1-tosyl-1H-indole		E Param.: -14.60	Chem. Commun. 2021, 57, 10071-10074 10.1039/d1cc04074j
4-bromo-<i>trans-beta</i>-nitrostyrene		E Param.: -13.37	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-chlorobenzaldehyde-boron trichloride complex		E Param.: 1.44, Deviation: ±0.20	Acc. Chem. Res. 2003, 36, 66-77 10.1021/ar020094c
4-cyano-6-nitro-benzofuroxane		E Param.: -6.41, Deviation: ±0.38	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-cyano-<i>trans-beta</i>-nitrostyrene		E Param.: -12.61	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-fluoro-benzaldehyde (in DMSO)	DMSO		J. Am. Chem. Soc. 2011, 133, 8240-8251 10.1021/ja200820m
4-methoxy-<i>trans-beta</i>-nitrostyrene		E Param.: -14.70	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-methyl-<i>trans-beta</i>-nitrostyrene		E Param.: -14.23	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-nitro-6-(trifluoromethylsulfonyl)benzofuroxan		E Param.: -4.91, Deviation: ±0.31	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
4-nitro-<i>trans-beta</i>-nitrostyrene		E Param.: -12.37	J. Org. Chem. 2011, 76, 9370-9378 10.1021/jo201678u
4-nitrobenzodifuroxan (NBDF)		E Param.: -6.15	Chem. Eur. J. 2007, 13, 8317-8324 10.1002/chem.200700676
4-phenylbut-3-yn-2-one		E Param.: -16.90	Angew. Chem. Int. Ed. 2019, 58, 17704-17708 10.1002/anie.201909803
5,7,7-trichloro-8(7H)-quinolinone	MeCN	E Param.: -10.48	Org. Lett. 2010, 12, 2238-2241 10.1021/ol100592j
5-methoxyfuroxano[3,4-d]pyrimidine		E Param.: -8.37	J. Phys. Org. Chem. 2003, 16, 431-437 10.1002/poc.606
6-cyano-4-nitrobenzofuroxan		E Param.: -7.01, Deviation: ±0.16	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
6-nitro-tetrazolo[1,5a]pyridine		E Param.: -9.05, Deviation: ±0.12	J. Org. Chem. 2005, 70, 6242-6253 10.1021/jo0505526
9-(4-(dimethylamino)phenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: -4.51	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963
9-(4-methoxyphenyl)-9H-fluoren-9-ylium	dichloromethane	E Param.: 0.85	Chem. Eur. J. 2017, 23, 623-630 10.1002/chem.201603963