Mayr's Database of Reactivity Parameters

Enamines, Enamides, and Ynamides

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
3-pyrrolidino-1H-indene (in MeCN)
 C13H15N *
MeCN

N  Param.: 15.27

sN Param.: 0.93
*** Synthesis 2019, 51, 1157-1170
10.1055/s-0037-1611634
4-(bis(trimethylsiloxy)amino)pent-4-enoic acid methyl ester
C12H27NO4Si2 *
dichloromethane

N  Param.: 3.84

sN Param.: 0.87
*** J. Org. Chem. 2001, 66, 3196-3200
10.1021/jo0015927
4-methyl-N-(2-phenylethynyl)-N-(phenylmethyl)benzenesulfonamide
C22H19NO2S *
dichloromethane

N  Param.: 3.85

sN Param.: 0.84
*** Angew. Chem. Int. Ed. 2014, 53, 4968-4971
10.1002/anie.201402055
alpha-(N-morpholino)styrene
C12H15NO *
dichloromethane

N  Param.: 9.96

sN Param.: 0.79
*** Chem. Eur. J. 2003, 9, 2209-2218
10.1002/chem.200204666
alpha-(N-morpholino)styrene (in MeCN)
C12H15NO *
MeCN

N  Param.: 10.30

sN Param.: 0.80
* Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
alpha-(N-piperidino)styrene (in MeCN)
C13H17N *
MeCN

N  Param.: 11.60

sN Param.: 0.80
* Chem. Eur. J. 2018, 24, 5901-5910
10.1002/chem.201705962
benzyl (1-phenylvinyl)carbamate
C16H15NO2 *
MeCN

N  Param.: 6.21

sN Param.: 0.87
*** Chem. Eur. J. 2012, 18, 5732-5740
10.1002/chem.201103519
ethyl (E)-3-(dimethylamino)acrylate
C7H13NO2 *
dichloromethane

N  Param.: 9.43

sN Param.: 0.80
* Chem. Eur. J. 2003, 9, 2209-2218
10.1002/chem.200204666
ethyl (E)-3-(N-morpholino)acrylate
C9H15NO3 *
dichloromethane

N  Param.: 8.52

sN Param.: 0.80
* Chem. Eur. J. 2003, 9, 2209-2218
10.1002/chem.200204666
methyl (cyclohexen-1-yl)prolinate (in MeCN)
*
MeCN

N  Param.: 14.96

sN Param.: 0.68
*** Angew. Chem. Int. Ed. 2010, 49, 9526-9529
10.1002/anie.201004344