Carbanions
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
anion of 4-methylbenzyl trifluoromethyl sulfone (in DMSO)   |
DMSO | N Param.: 19.35 sN Param.: 0.67 |
 |
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in 91M9AN)  |
MeOH-MeCN mix | N Param.: 18.24 sN Param.: 0.66 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 14.49 sN Param.: 0.86 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |
anion of 4-nitrobenzyl-CN (in DMSO)  |
DMSO | N Param.: 19.67 sN Param.: 0.68 |
|
J. Org. Chem. 2009, 74, 75-81 10.1021/jo802241x |
anion of 4-nitrobenzyl-CN (in MeCN)  |
MeCN | N Param.: 20.10 sN Param.: 0.71 |
|
J. Am. Chem. Soc. 2020, 142, 8383-8402 10.1021/jacs.0c01960 |
anion of 5-(p-anisyl) Meldrum's acid (in DMSO)  |
DMSO | N Param.: 12.35 sN Param.: 0.90 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of 5-phenyl Meldrum's acid (in DMSO)  |
DMSO | N Param.: 11.54 sN Param.: 0.95 |
|
Eur. J. Org. Chem. 2016, , 1841-1848 10.1002/ejoc.201600107 |
anion of acetylacetone (in DMSO)  |
DMSO | N Param.: 17.64 sN Param.: 0.73 |
|
Angew. Chem. Int. Ed. 2002, 41, 91-95 10.1002/1521-3773(20[...] |
anion of acetylacetone (in water)  |
water | N Param.: 13.73 sN Param.: 0.64 |
|
J. Am. Chem. Soc. 2003, 125, 12980-12986 10.1021/ja036838e |
anion of benzyl trifluoromethyl sulfone (in DMSO)  |
DMSO | N Param.: 18.67 sN Param.: 0.68 |
|
J. Am. Chem. Soc. 2007, 129, 9753-9761 10.1021/ja072135b |