Mayr's Database of Reactivity Parameters

Carbanions

For reactivities of structurally related compounds go to: Nucleophiles » C-Nucleophiles » Carbanions

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
anion of (3-nitrophenyl)nitromethane (in DMSO)
C7H5N2O4- *
 DMSO

N  Param.: 18.06

sN Param.: 0.71		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (3-nitrophenyl)nitromethane (in water)
C7H5N2O4- *
 water

N  Param.: 14.25

sN Param.: 0.46		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-CF3-C6H4)CH2SO2Ph (in DMSO)
C14H10F3O2S- *
 DMSO

N  Param.: 24.30

sN Param.: 0.51		 *** Org. Biomol. Chem. 2008, 6, 3052-3058
10.1039/b805604h
anion of (4-CN-C6H4)CH2SO2Ph (in DMSO)
C14H10NO2S- *
 DMSO

N  Param.: 22.60

sN Param.: 0.57		 *** Org. Biomol. Chem. 2008, 6, 3052-3058
10.1039/b805604h
anion of (4-cyanophenyl)nitromethane (in 91M9AN)
C8H5N2O2- *
 MeOH-MeCN mix

N  Param.: 13.92

sN Param.: 0.74		 *** Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of (4-cyanophenyl)nitromethane (in DMSO)
C8H5N2O2- *
 DMSO

N  Param.: 16.96

sN Param.: 0.73		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-cyanophenyl)nitromethane (in water)
C8H5N2O2- *
 water

N  Param.: 13.23

sN Param.: 0.52		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-nitrophenyl)nitromethane (in 91M9AN)
C7H5N2O4- *
 MeOH-MeCN mix

N  Param.: 14.05

sN Param.: 0.72		 *** Eur. J. Org. Chem. 2006, , 2530-2537
10.1002/ejoc.200500769
anion of (4-nitrophenyl)nitromethane (in DMSO)
C7H5N2O4- *
 DMSO

N  Param.: 16.29

sN Param.: 0.75		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j
anion of (4-nitrophenyl)nitromethane (in water)
C7H5N2O4- *
 water

N  Param.: 13.58

sN Param.: 0.52		 *** J. Org. Chem. 2004, 69, 7565-7576
10.1021/jo048773j