Carbanions in DMSO
| Name | Solvent |
Reactivity Parameters |
Classification |
Reference (title or year) |
|---|---|---|---|---|
bromo(phenylsulfonyl)methanide (in DMSO)   |
DMSO | N Param.: 23.90 sN Param.: 0.62 |
 |
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-chlorophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 26.90 sN Param.: 0.45 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-cyanophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 25.59 sN Param.: 0.51 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro((4-nitrophenyl)sulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 24.88 sN Param.: 0.49 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
chloro(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 28.27 sN Param.: 0.42 |
|
J. Org. Chem. 2017, 82, 2011-2017 10.1021/acs.joc.6b02844 |
cyano((diphenylmethylene)amino)methanide  |
DMSO | N Param.: 29.50 sN Param.: 0.50 |
|
Tetrahedron 2019, 75, 459-463 10.1016/j.tet.2018.1[...] |
enolate of 2-coumaranone (in DMSO)  |
DMSO | N Param.: 19.60 sN Param.: 0.75 |
|
J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277 |
enolate of 3-isochromanone (in DMSO)  |
DMSO | N Param.: 25.39 sN Param.: 0.54 |
|
J. Org. Chem. 2024, 89, 6915-6928 10.1021/acs.joc.4c00277 |
fluorobis(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 17.46 sN Param.: 0.73 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
lithium indenide (in DMSO)  |
DMSO | N Param.: 23.66 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2015, 54, 12497-12500 10.1002/anie.201501385 |
MeSO-CH-CO2Et (in DMSO)  |
DMSO | N Param.: 20.61 sN Param.: 0.64 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
MeSO2-CH-CO2Et (in DMSO)  |
DMSO | N Param.: 18.00 sN Param.: 0.66 |
|
Chem. Eur. J. 2010, 16, 8610-8614 10.1002/chem.201001455 |
methoxybis(phenylsulfonyl)methanide (in DMSO)  |
DMSO | N Param.: 17.29 sN Param.: 0.70 |
|
Angew. Chem. Int. Ed. 2016, 55, 12845-12848 10.1002/anie.201605616 |
Ph2P(O)CH(-)CN (in DMSO)  |
DMSO | N Param.: 18.69 sN Param.: 0.72 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
Ph2P(O)CH(-)CO2Et (in DMSO)  |
DMSO | N Param.: 19.20 sN Param.: 0.69 |
|
J. Am. Chem. Soc. 2009, 131, 704-714 10.1021/ja8056216 |
potassium indenide (in DMSO)  |
DMSO | N Param.: 24.16 sN Param.: 0.68 |
|
Angew. Chem. Int. Ed. 2015, 54, 12497-12500 10.1002/anie.201501385 |
sodium indenide (in DMSO)  |
DMSO | N Param.: 23.74 sN Param.: 0.71 |
|
Angew. Chem. Int. Ed. 2015, 54, 12497-12500 10.1002/anie.201501385 |