Mayr's Database of Reactivity Parameters

Carbanions in DMSO

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
5-(4-(methoxy)benzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C14H15O5 *
DMSO

N  Param.: 15.13

sN Param.: 0.75
*** Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
5-benzyl-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C13H13O4 *
DMSO

N  Param.: 15.02

sN Param.: 0.75
*** Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
5-(4-cyanobenzyl)-2,2-dimethyl-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C14H12NO4 *
DMSO

N  Param.: 13.79

sN Param.: 0.86
*** Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
2,2-dimethyl-5-(4-nitrobenzyl)-4,6-dioxo-1,3-dioxan-5-ide (in DMSO)
C13H12NO6 *
DMSO

N  Param.: 12.02

sN Param.: 1.17
*** Chem. Eur. J. 2014, 20, 11069-11077
10.1002/chem.201403161
anion of 1,2-diphenylethanone (in DMSO)
C14H11O *
DMSO

N  Param.: 23.15

sN Param.: 0.60
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of N,N-diethyl-3-oxo-3-phenylpropanoate (in DMSO)
C13H16NO2 *
DMSO

N  Param.: 19.28

sN Param.: 0.65
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of ethyl 3-oxo-3-phenylpropanoate (in DMSO)
C11H11O3 *
DMSO

N  Param.: 17.52

sN Param.: 0.74
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of 3-oxo-3-phenylpropanenitrile (in DMSO)
C9H6NO *
DMSO

N  Param.: 16.55

sN Param.: 0.78
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of 1-phenylbutane-1,3-dione (in DMSO)
C10H9O2 *
DMSO

N  Param.: 16.03

sN Param.: 0.86
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500
anion of 1,3-diphenylpropane-1,3-dione (in DMSO)
C15H11O2 *
DMSO

N  Param.: 17.46

sN Param.: 0.65
*** Chem. Eur. J. 2015, 21, 875-884
10.1002/chem.201404500