Mayr's Database of Reactivity Parameters

Alkenes

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
1-hexene
C6H12 *
dichloromethane

N  Param.: -2.77

sN Param.: 1.41
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
1-methyl-4-vinyl-benzene
C9H10 *
dichloromethane

N  Param.: 1.70

sN Param.: 1.06
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-methylcyclohexene
C7H12 *
dichloromethane

N  Param.: 0.08

sN Param.: 1.15
***** J. Am. Chem. Soc. 2001, 123, 9500-9512
10.1021/ja010890y
1-methylcyclopentene
C6H10 *
dichloromethane

N  Param.: 1.18

sN Param.: 1.17
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3,3-trimethyl-but-1-ene
C7H14 *
dichloromethane

N  Param.: 0.06

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3-dimethyl-but-1-ene
C6H12 *
dichloromethane

N  Param.: 0.65

sN Param.: 1.00
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,3-dimethyl-buta-1,3-diene
C6H10 *
dichloromethane

N  Param.: 1.17

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c
2,4,4-trimethyl-pent-1-ene
C8H16 *
dichloromethane

N  Param.: 0.79

sN Param.: 1.07
***** J. Am. Chem. Soc. 2012, 134, 13902-13911
10.1021/ja306522b
2,4,6-trimethylstyrene
C11H14 *
dichloromethane

N  Param.: 0.68

sN Param.: 1.09
*** Macromolecules 2005, 38, 33-40
10.1021/ma048389o
2,4-dimethyl-penta-1,4-diene
C7H12 *
dichloromethane

N  Param.: 0.54

sN Param.: 1.00
* Acc. Chem. Res. 2003, 36, 66-77
10.1021/ar020094c