Mayr's Database of Reactivity Parameters

H-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
(4-methoxyphenyl)dimethylsilane
C9H14OSi *
dichloromethane

N  Param.: 4.23

sN Param.: 0.73
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(chloromethyl)dimethylsilane
C3H9ClSi *
dichloromethane

N  Param.: 0.80

sN Param.: 0.73
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(E,E)-2,5-heptadiene
C7H12 *
dichloromethane

N  Param.: -0.74

sN Param.: 0.99
*** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
C9H28Si4 *
dichloromethane

N  Param.: 3.61

sN Param.: 0.79
*** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1,1,3,3-pentamethyldisiloxane
C5H16OSi2 *
dichloromethane

N  Param.: 3.12

sN Param.: 0.73
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilepane
*
dichloromethane

N  Param.: -3.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsiletane
*
dichloromethane

N  Param.: -2.10

sN Param.: 1.10
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilinane
C7H16Si *
dichloromethane

N  Param.: -2.40

sN Param.: 1.10
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,1-dimethylsilolane
*
dichloromethane

N  Param.: -3.86

sN Param.: 1.10
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,2,4,5-tetramethylcyclohexa-1,4-diene (in CH2Cl2)
C10H16 *
dichloromethane

N  Param.: 4.27

sN Param.: 0.86
** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y