Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
methyl(neopentyl)(phenyl)silane
C12H20Si *
 dichloromethane

N  Param.: 0.87

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(3-chlorobenzyl)dimethylsilane
C9H13ClSi *
 dichloromethane

N  Param.: 1.30

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraisobutylstannane
*
 dichloromethane

N  Param.: 1.35

sN Param.: 1.10		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HMn(CO)5
*
 dichloromethane

N  Param.: 1.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
diphenylsilane
*
 dichloromethane

N  Param.: 1.52

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HCr(CO)3Cp*
*
 dichloromethane

N  Param.: 1.60

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
HW(CO)3Cp
*
 dichloromethane

N  Param.: 1.70

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2)
C8H12 *
 dichloromethane

N  Param.: 1.88

sN Param.: 0.96		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
methyl(phenyl)silane
C7H10Si *
 dichloromethane

N  Param.: 2.13

sN Param.: 0.73		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1-methylsilolane
C5H12Si *
 dichloromethane

N  Param.: 2.20

sN Param.: 0.75		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839