Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C10H21N2P *
 MeCN

N  Param.: 25.54

sN Param.: 0.35		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-2,3-dihydro-1H-benzo[d][1,3,2]diazaphosphole (in MeCN)
C14H23N2P *
 MeCN

N  Param.: 20.93

sN Param.: 0.43		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C26H37N2P *
 MeCN

N  Param.: 19.85

sN Param.: 0.34		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-di-tert-butyl-1,3,2-diazaphospholidine (in MeCN)
C10H23N2P *
 MeCN

N  Param.: 18.74

sN Param.: 0.47		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
1,3-dimesityl-2,3-dihydro-1H-1,3,2-diazaphosphole (in MeCN)
C20H25N2P *
 MeCN

N  Param.: 17.68

sN Param.: 0.68		 *** Angew. Chem. Int. Ed. 2019, 58, 5983-5987
10.1002/anie.201901456
KBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 15.14

sN Param.: 0.77		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
Bu4NBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 14.94

sN Param.: 0.79		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
NaBH4 (in DMSO)
BH4- *
 DMSO

N  Param.: 14.74

sN Param.: 0.81		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
NaB(OAc)3H (in DMSO)
C6H10BO6- *
 DMSO

N  Param.: 14.45

sN Param.: 0.76		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
[H-B(2,4,6-F3C6H2)3]- [NEt4]+
*
 MeCN

N  Param.: 14.13

sN Param.: 0.61		 *** Angew. Chem. Int. Ed. 2015, 54, 14508-14512
10.1002/anie.201507298