Mayr's Database of Reactivity Parameters

H-Nucleophiles

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Name Solvent Reactivity
Parameters
Classification Reference
(title or year)
2-(p-tolyl)-1,3-dimethyl-benzimidazoline
*
MeCN

N  Param.: 10.14

sN Param.: 0.70
*** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-ethyl-4,5-dimethyl-1,3-dioxolane (anti)
*
dichloromethane

N  Param.: -2.90

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn)
*
dichloromethane

N  Param.: -2.40

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-isopropyl-4,5-dimethyl-1,3-dioxolane (ani)
*
dichloromethane

N  Param.: -4.10

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-isopropyl-4,5-dimethyl-1,3-dioxolane (syn)
*
dichloromethane

N  Param.: -3.50

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-methyl-1,3-dioxolane
*
dichloromethane

N  Param.: -3.30

sN Param.: 0.80
- Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyl-1,3-dimethyl-benzimidazoline
*
MeCN

N  Param.: 9.72

sN Param.: 0.72
*** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-phenyldioxolane
C9H10O2 *
dichloromethane

N  Param.: -0.90

sN Param.: 0.80
* Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-propyl-1,3-dioxolane
C6H12O2 *
dichloromethane

N  Param.: -1.06

sN Param.: 0.81
*** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
3-methyl-1,4-pentadiene
C6H10 *
dichloromethane

N  Param.: -3.08

sN Param.: 0.97
* J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538