Mayr's Database of Reactivity Parameters

H-Nucleophiles

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
bis(4-(dimethylamino)phenyl)phenylmethane (in MeCN)
C23H26N2 *
 MeCN

N  Param.: -4.20

sN Param.: 0.82		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
bis(4-methoxyphenyl)methane (in CH2Cl2)
C15H16O2 *
 dichloromethane

N  Param.: -2.11

sN Param.: 0.98		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
bis(4-methoxyphenyl)phenylmethane (in MeCN)
C21H20O2 *
 MeCN

N  Param.: -7.00

sN Param.: 0.82		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-2,6-lutidine-complex
*
 dichloromethane

N  Param.: 10.33

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-methoxypyridine-complex
*
 dichloromethane

N  Param.: 11.01

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-4-tBu-pyridine-complex
*
 dichloromethane

N  Param.: 10.46

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-DMAP-complex
*
 dichloromethane

N  Param.: 12.44

sN Param.: 0.76		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N,N-diethylaniline-complex
*
 dichloromethane

N  Param.: 8.53

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N,N-diisopropylaniline-complex
*
 dichloromethane

N  Param.: 8.84

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
borane-N-ethyl-N-isopropylaniline-complex
*
 dichloromethane

N  Param.: 9.12

sN Param.: 0.75		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839