Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dihydronaphthalene
C10H10 *
 dichloromethane

N  Param.: -0.07

sN Param.: 1.03		 *** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-dihydronaphthalene (in MeCN)
C10H10 *
 MeCN

N  Param.: -2.50

sN Param.: 1.00		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dimethylcyclohexa-1,4-diene (in CH2Cl2)
C8H12 *
 dichloromethane

N  Param.: 1.88

sN Param.: 0.96		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,4-pentadiene
C5H8 *
 dichloromethane

N  Param.: -2.99

sN Param.: 0.97		 * J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,6-bis(trimethylsilyl)hexane
*
 dichloromethane

N  Param.: -4.70

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
10-methyl-9,10-dihydroacridine
*
 dichloromethane

N  Param.: 5.54

sN Param.: 0.90		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
10-methyl-9,10-dihydroacridine (in MeCN)
C14H13N *
 MeCN

N  Param.: 4.00

sN Param.: 0.70		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -3.00

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2,4,5-trimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839