Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
diethylmercury (in MeCN)
*
 MeCN

N  Param.: -0.70

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
dimethoxymethane
*
 dichloromethane

N  Param.: -4.90

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
Hantzsch ester
C13H19NO4 *
 dichloromethane

N  Param.: 9.00

sN Param.: 0.90		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
isopropanol (in aq. sulfuric acid)
C3H8O *
 water

N  Param.: -2.60

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-(p-anisyl)-1,4-dihydronicotineamide
C13H14N2O2 *
 dichloromethane

N  Param.: 8.11

sN Param.: 0.92		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-(p-tolyl)-1,4-dihydronicotineamide
C13H14N2O *
 dichloromethane

N  Param.: 7.68

sN Param.: 0.95		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-benzyl-1,4-dihydronicotineamide
C13H14N2O *
 dichloromethane

N  Param.: 8.67

sN Param.: 0.82		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
N-benzyl-1,4-dihydronicotineamide (in 50W50AN)
*
 water-MeCN mix

N  Param.: 9.79

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 67W33AN)
*
 water-MeCN mix

N  Param.: 10.19

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 80W20AN)
*
 water-MeCN mix

N  Param.: 10.67

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839