Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
tetraethylstannane (in MeCN)
*
 MeCN

N  Param.: -2.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylstannyl)propyl)germane (in MeCN)
*
 MeCN

N  Param.: -2.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
4,5-dimethyl-1,3-dioxolane (anti)
*
 dichloromethane

N  Param.: -2.40

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-ethyl-4,5-dimethyl-1,3-dioxolane (syn)
*
 dichloromethane

N  Param.: -2.40

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
bis(4-methoxyphenyl)methane (in CH2Cl2)
C15H16O2 *
 dichloromethane

N  Param.: -2.11

sN Param.: 0.98		 ** J. Am. Chem. Soc. 2014, 136, 13863-13873
10.1021/ja507598y
1,1-dimethylsiletane
*
 dichloromethane

N  Param.: -2.10

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraethylstannane (in 1,2-DCE)
*
 1,2-dichloroethane

N  Param.: -1.90

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-chlorophenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: -1.80

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,3-bis(trimethylstannyl)propane (in MeCN)
*
 MeCN

N  Param.: -1.70

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylplumbyl)propyl)silane (in MeCN)
*
 MeCN

N  Param.: -1.20

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839