Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
diethylmercury (in MeCN)
*
 MeCN

N  Param.: -0.70

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrapropylstannane (in 1,2-DCE)
*
 1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.13		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(4-methylphenethyl)stannane
*
 1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrabutylstannane
*
 dichloromethane

N  Param.: -0.30

sN Param.: 1.07		 *** Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-(tert-butyl)phenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: -0.30

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-dihydronaphthalene
C10H10 *
 dichloromethane

N  Param.: -0.07

sN Param.: 1.03		 *** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
1,4-cyclohexadiene
C6H8 *
 dichloromethane

N  Param.: 0.09

sN Param.: 0.98		 *** J. Am. Chem. Soc. 2002, 124, 4076-4083
10.1021/ja0121538
tetraethylplumbane (in MeCN)
*
 MeCN

N  Param.: 0.10

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
(4-methoxyphenethyl)trimethylstannane
*
 1,2-dichloroethane

N  Param.: 0.20

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
1,4-cyclohexadiene (in MeCN)
*
 MeCN

N  Param.: 0.35

sN Param.: 0.98		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839