Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
tetraethylsilane
*
 MeCN

N  Param.: -6.50

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraethylstannane (in 1,2-DCE)
*
 1,2-dichloroethane

N  Param.: -1.90

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraethylstannane (in MeCN)
*
 MeCN

N  Param.: -2.40

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrahydrofuran (in dichloromethane)
C4H8O *
 dichloromethane

N  Param.: -3.50

sN Param.: 0.80		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetraisobutylstannane
*
 dichloromethane

N  Param.: 1.35

sN Param.: 1.10		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tetrapropylstannane (in 1,2-DCE)
*
 1,2-dichloroethane

N  Param.: -0.50

sN Param.: 1.13		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tri-p-tolylmethane
*
 dichloromethane

N  Param.: -3.62

sN Param.: 0.80		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
tri-p-tolylmethane (in MeCN)
C22H22 *
 MeCN

N  Param.: -8.80

sN Param.: 0.82		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylgermyl)propyl)silane (in MeCN)
*
 MeCN

N  Param.: -4.80

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
trimethyl(3-(trimethylplumbyl)propyl)germane (in MeCN)
*
 MeCN

N  Param.: -1.00

sN Param.: 1.10		 - Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839