Mayr's Database of Reactivity Parameters

H-C hydride donors

For reactivities of structurally related compounds go to: Nucleophiles » H-Nucleophiles » H-C hydride donors

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Name Solvent Reactivity
Parameters 		Classification Reference
(title or year)
N-benzyl-1,4-dihydronicotineamide (in 90W10AN)
C13H14N2O *
 water-MeCN mix

N  Param.: 11.35

sN Param.: 0.66		 *** Angew. Chem. Int. Ed. 2009, 48, 1958-1961
10.1002/anie.200804263
NADPH (in water)
*
 water

N  Param.: 10.68

sN Param.: 0.54		 *** Org. Biomol. Chem. 2023, 21, 85-88
10.1039/D2OB02041F
N-benzyl-1,4-dihydronicotineamide (in 80W20AN)
*
 water-MeCN mix

N  Param.: 10.67

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
NADH (in water)
*
 water

N  Param.: 10.37

sN Param.: 0.54		 *** Org. Biomol. Chem. 2023, 21, 85-88
10.1039/D2OB02041F
N-benzyl-1,4-dihydronicotineamide (in 67W33AN)
*
 water-MeCN mix

N  Param.: 10.19

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-(p-tolyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.14

sN Param.: 0.70		 *** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
2-(p-anisyl)-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 10.01

sN Param.: 0.72		 *** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322
N-benzyl-1,4-dihydronicotineamide (in MeCN)
*
 MeCN

N  Param.: 9.80

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
N-benzyl-1,4-dihydronicotineamide (in 50W50AN)
*
 water-MeCN mix

N  Param.: 9.79

sN Param.: 0.70		 * Chem. Eur. J. 2013, 19, 249-263
10.1002/chem.201202839
2-phenyl-1,3-dimethyl-benzimidazoline
*
 MeCN

N  Param.: 9.72

sN Param.: 0.72		 *** Chem. Asian J. 2009, 4, 1824-1829
10.1002/asia.200900322